IRAMIS/DIR – Adjointe scientifique au Directeur de l’Institut IRAMIS
Service de Physique de l’Etat Condensé (SPEC, UMR 3680)
Laboratoire d’Electronique et nanoPhotonique Organique (LEPO)
Fonctions
Chercheur en nanoPhotonique (ORCID),
Adjointe à la Direction de l’Institu IRAMIS (2023 – )
Adjointe à la Direction du SPEC (2014 – 2023)
Coordinatrice du LabEx NanoSaclay (http://www.nanosaclay.fr/) (2019 – 2023)
Expert Senior CEA
Membre du comité de rédaction de Photoniques, la revue de la SFO
Présidente du Club SFO « HORIZONs de l’Optique«
Sujets de recherche
- Optique et nanophotonique non-linéaire en milieu organique (fluorescence, absorption multiphotonique, conversion de fréquence …)
- Nano-antennes optiques et plasmonique moléculaire
- Microstructuration de polymères par voie optique
- Étude de l’organisation de la matière à différentes échelles par des techniques conjointes de spectroscopie et de microscopie à sonde locale (STM, AFM)
– Applications : marquage de l’ADN, optimisation de composants optoélectroniques (cellules solaires plastiques, diodes organiques électroluminescentes, capteurs chimiques).
Cursus
2004- Chercheur CEA,Direction des Sciences de la Matière / DRECAM/SPCSI puis IRAMIS/SPEC/LEPO
1995-2004 Chercheur CEA, Direction de la Recherche Technologique / Laboratoire Composants Organiques
2009 : Habilitation à Diriger des Recherches (Université Paris VI-Jussieu) – « Contrôle optique de l’organisation de matériaux moléculaires : de l’échelle microscopique à la manipulation de molécules individuelles »
1992–1995 : Thèse en Sciences Physiques, optique et photonique (Paris XI-Orsay), CEA Saclay (DTA/DEIN)
« Étude des non-linéarités du second ordre induites par voie optique, application à l’orientation optique de molécules organiques. »
1989 – 1992 : École Supérieure d’Optique , Orsay (now IOGS)
Publications scientifiques
~100 publications dans des revues à comité de lecture, Hirsh factor=35
Publications dans la base HAL – Open access
- Ge, D., Marguet, S., Issa, A., S. Jradi, H. Nguyen, M. Nahra, J. Béal, R. Deturche, H. Chen, S. Blaize, J. Plain, C. Fiorini, L. Douillard, O. Soppera, Q. Dinh Xuan, C. Dang, X. Yang, T. Xu, B. Wei, X. Wei Sun, C. Couteau, and R. Bachelot, Hybrid plasmonic nano-emitters with controlled single quantum emitter positioning on the local excitation field, Nature Commun. 11, 3414 (2020).
- F. Kameche, W. Heni, S. Telitel, D. Ge, L. Vidal, F. Dumur, D. Gigmes, J. Lalevée, S. Marguet, L. Douillard, C. Fiorini-Debuisschert, R. Bachelot, O. Soppera, Plasmon-triggered living photopolymerization for elaboration of hybrid polymer/metal nanoparticles, Materials Today (2020).
- N. Kalashnyk, M. Jaouen, C. Fiorini-Debuisschert, L. Douillard, AJ Attias, and F Charra, Electronic effects of the Bernal stacking of graphite on self-assembled aromatic adsorbates, Chem Comm 54, 9607 (2018).
- Molinaro C, Marguet S, Douillard L, Charra F and Fiorini-Debuisschert C From plasmon-induced luminescence enhancement in gold nanorods to plasmon-induced luminescence turn-off: a way to control reshaping Phys Chem Chem Phys 20, 12295 (2018). DOI: 10.1039/c8cp00867a
- Brigita Rožič,Jérôme Fresnais, Celine Molinaro,Joseph Calixte,Shivakumar Umadevi, Stephanie Lau-Truong,Nordin Felidj, Tobias Kraus,Fabrice Charra, Vincent Dupuis,Torsten Hegmann, Celine Fiorini-Debuisschert, Bruno Gallas and Emmanuelle Lacaze, Oriented Gold Nanorods and Gold Nanorod Chains within Smectic Liquid Crystal Topological Defects, ACS Nano, DOI: 10.1021/acsnano.7b01132, (2017).
- Sylvain Le Liepvre,Ping Du,David Kreher,Fabrice Mathevet, André-Jean Attias, Céline Fiorini-Debuisschert, Ludovic Douillard,and Fabrice Charra, Fluorescent Self-Assembled Molecular Monolayer on Graphene, ACS Photonics , DOI: 10.1021/acsphotonics.6b00793, (2016)
- Molinaro, C ; Yara El Harfouch, Etienne Palleau, Fabien Eloi, Sylvie Marguet, Ludovic Douillard, Fabrice Charra, Céline Fiorini-Debuisschert, Two-Photon Luminescence of Single Colloidal Gold NanoRods: Revealing the Origin of Plasmon Relaxation in Small Nanocrystals, J. PHYS CHEM C, DOI 10.1021/acs.jpcc.6b07498, (2016)
- Sghaier, T; Le Liepvre, S; Fiorini, C; Douillard, L; Charra, F, Optical absorption signature of a self-assembled dye monolayer on graphene, BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 7, 862 (2016). doi:10.3762/bjnano.7.78
- Alexis Depauw, Elena Dossi, Naresh Kumar, Céline Fiorini-Debuisschert, Gilles Huberfeld, Minh-Huong Ha-Thi, Nathalie Rouach and Isabelle Leray, A highly selective potassium sensor for the detection of potassium in living tissues, CHEMISTRY – A EUROPEAN JOURNAL, 22, 14902, DOI : 10.1002/chem.201602209, (2016)
- Dumat, B; Faurel-Paul, E; Fornarelli, P; Saettel, N; Metge, G; Fiorini-Debuisschert, C ; Charra, F; Mahuteau-Betzer, F; Teulade-Fichou, MP, Influence of the oxazole ring connection on the fluorescence of oxazoyl-triphenylamine biphotonic DNA probes, ORGANIC & BIOMOLECULAR CHEMISTRY, 14(1), 358, (2016). DOI: 10.1039/c5ob02225h
- Adrien Faucon, Thomas Maldiney, Olivier Clément, Philippe Hulin, Steven Nedellec, Myriam Robard, Nicolas Gautier, Evelien De Meulenaere, Koen Clays, Tomas Orlando, Alessandro Lascialfari, Céline Fiorini-Debuisschert, Jérôme Fresnais and Eléna Ishow, Highly cohesive dual nanoassemblies for complementary multiscale bioimaging, J. Mater. Chem. B, 2, 7747-7755 (2014)
- Bellec, A; Arrigoni, C; Douillard, L; Fiorini-Debuisschert, C; Mathevet, F; Kreher, D; Attias, AJ; Charra, F – Formation of hydroxyl-functionalized stilbenoid molecular sieves at the liquid/solid interface on top of a 1-decanol monolayer – Nanotechnology, Volume: 25, Issue: 43, Article Number: 435604, DOI: 10.1088/0957-4484/25/43/435604, (2014)
- Du, P; Jaouen, M; Bocheux, A; Bourgogne, C; Han, Z; Bouchiat, V; Kreher, D; Mathevet, F; Fiorini-Debuisschert, C; Charra, F; Attias, AJ –Surface-Confined Self-Assembled Janus Tectons: A Versatile Platform towards the Noncovalent Functionalization of Graphene – ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Volume: 53, Issue: 38, Pages: 10060-10066, DOI: 10.1002/anie.201403572, (2014)
- Hammerer, F; Garcia, G; Chen, S; Poyer, F; Achelle, S; Fiorini-Debuisschert,C; Teuade-Fichou, MP; Maillard, P, Synthesis and Characterization of Glycoconjugated Porphyrin Triphenylamine Hybrids for Targeted Two-Photon Photodynamic Therapy, J. Org. Chem, Volume: 79, Issue: 3, Pages: 1406-1417, DOI: 10.1021/jo402658h, (2014)
- Zhou, X; Deeb, C; Vincent, R; Lerond, T; Adam, PM; Plain, J; Wiederrecht, GP; Charra, F; Fiorini, C; des Francs, GC; Soppera, O; Bachelot, R – Polarization-dependent fluorescence from an anisotropic gold/polymer hybrid nano-emitter– Appl. Phys Lett, Volume: 104, Issue: 2, Article Number: 023114, DOI: 10.1063/1.4861898, (2014).
- Dumat, B; Bordeau, G; Faurel-Paul, E; Mahuteau-Betzer, F; Saettel, N; Metge, G; Fiorini-Debuisschert, C; Charra, F; Teulade-Fichou, MP – Switches on the Two-Photon Efficiency of an Ultrabright Triphenylamine Fluorescent Probe Specific of AT Regions – J. Am. Chem. Soc, Volume: 135, Issue: 34, Pages: 12697-12706, DOI: 10.1021/ja404422z, (2013).
- Bleger, D; Bocheux, A; Kreher, D; Mathevet, F; Attias, AJ ; Metge, G; Douillard, L; Fiorini-Debuisschert, C; Charra, F – An optimized alkyl chain-based binding motif for 2D self-assembly: a comprehensive crystallographic approach – NanoScale, Volume: 5, Issue: 4, Pages: 1452-1455, DOI: 10.1039/c2nr33509c (2013).
- Dumat, B; Bordeau, G; Aranda, AI; Mahuteau-Betzer, F; El Harfouch, Y ; Metge, G; Charra, F; Fiorini-Debuisschert, C; Teulade-Fichou, MP , Vinyl-triphenylamine dyes, a new family of switchable fluorescent probes for targeted two-photon cellular imaging: from DNA to protein labeling – Org. and Biomolec. Chem.- Volume: 10, Issue: 30, Pages: 6054-6061, DOI: 10.1039/c2ob25515d (2012).
- Bocheux, A; Tahar-Djebbar, I; Fiorini-Debuisschert, C; Douillard, L; Mathevet, F; Attias, AJ; Charra, F , Self-Templating Polythiophene Derivatives: Electronic Decoupling of Conjugated Strands through Staggered Packing –Langmuir -Volume: 27, Issue: 16, Pages: 10251-10255, DOI: 10.1021/la201743d (2011).
- Dumat, B; Bordeau, G; Faurel-Paul, E; Mahuteau-Betzer, F; Saettel, N; Bombled, M; Metge, G; Charra, F; Fiorini-Debuisschert, C; Teulade-Fichou, MP, N-phenyl-carbazole-based two-photon fluorescent probes: Strong sequence dependence of the duplex vs quadruplex selectivity –Biochimie -Volume: 93, Issue: 8, Pages: 1209-1218, DOI: 10.1016/j.biochi.2011.05.035 (2011).
- Bellec, A; Arrigoni, C; Schull, G; Douillard, L; Fiorini-Debuisschert, C; Mathevet, F; Kreher, D; Attias, AJ; Charra, F, Solution-growth kinetics and thermodynamics of nanoporous self-assembled molecular monolayers, J. Chem Phys, Volume: 134, Issue: 12, Article Number: 124702, DOI: 10.1063/1.3569132, (2011)
- Bleger, D; Mathevet, F; Kreher, D; Attias, AJ; Bocheux, A; Latil, S; Douillard, L; Fiorini-Debuisschert, C ; Charra, F, Janus-Like 3D Tectons: Self-Assembled 2D Arrays of Functional Units at a Defined Distance from the Substrate – ANGEWANDTE CHEMIE-INTERNATIONAL EDITION -Volume: 50, Issue: 29, Pages: 6562-6566, DOI: 10.1002/anie.201008212 (2011).
- Fiorini, C; Charra, F, Self-assembly: mastering photonic processes at nanoscale – OPTO-ELECTRONICS REVIEW, Volume: 18, Issue: 4, Pages: 376-383, DOI: 10.2478/s11772-010-0046-3 (2010).
- Arrigoni, C; Schull, G; Bleger, D; Douillard, L; Fiorini-Debuisschert, C; Mathevet, F; Kreher, D; Attias, AJ; Charra, F, Structure and Epitaxial Registry on Graphite of a Series of Nanoporous Self-Assembled Molecular Monolayers – J. Phys Chem Lett, Volume: 1, Issue: 1, Pages: 190-194, DOI: 10.1021/jz900146f (2010).
- Bordeau, G; Lartia, R; Metge, G; Fiorini-Debuisschert, C; Charra, F; Teulade-Fichou, MP, Trinaphthylamines as Robust Organic Materials for Two-Photon-Induced Fluorescence – J. Am. Chem. Soc, Volume: 130, Issue: 50, Pages: 16836-+, DOI: 10.1021/ja8055112 (2008)
- Berline, I; Fiorini-Debuisschert, C; Royal, C; Douillard, L; Charra, F, Molecular second harmonic generation induced at a metallic tip – J. Appl. Phys. -Volume: 104, Issue: 10, Article Number: 103113, DOI: 10.1063/1.3028265 (2008).
- Ishow, E; Brosseau, A; Clavier, G; Nakatani, K; Tauc, P; Fiorini-Debuisschert, C; Neveu, S; Sandre, O; Leaustic, A – Multicolor Emission of Small Molecule-Based Amorphous Thin Films and Nanoparticles with a Single Excitation Wavelength, Chem. Mat., Volume: 20, Issue: 21, Pages: 6597-6599, DOI: 10.1021/cm802264c (2008).
- Schull, G; Ness, H; Douillard, L; Fiorini-Debuisschert, C; Charra, F; Mathevet, F; Kreher, D (Kreher, David); Attiast, AJ, Atom substitution for marking and motion tracking of individual molecules by scanning tunneling microscopy, J. Phys Chem C, Volume: 112, Issue: 36, Pages: 14058-14063, DOI: 10.1021/jp8030013 (2008)
- Lartia, R; Allain, C; Bordeau, G; Schmidt, F; Fiorini-Debuisschert, C; Charra, F; Teulade-Fichou, MP, Synthetic strategies to derivatizable triphenylamines displaying high two-photon absorption, J. Org. Chem., Volume: 73, Issue: 5, Pages: 1732-1744, DOI: 10.1021/jo702002y (2008)
- D. Bleger, D. Kreher, F. Mathevet, AJ Attias, G. Schull, A. Huard, L Douillard, C. Fiorini-Debuisschert, F. Charra, A surface-activated non-covalent bonding for rational design of hierarchical molecular self-assemblies, Andegewandte Chem. Int. Ed., 46, 7404, (2007).
- C. Hubert , Fiorini-Debuisschert , L Rocha, et al., Spontaneous photoinduced patterning of azo-dye polymer films : the facts, J Opt Soc Am. B, 24 (8): 1839-1846 (2007).
- L. Douillard, F. Charra, C. Fiorini et al., Optical properties of metal nanoparticles as probed by photoemission electron microscopy, J. Appl. Phys., 101 (8) art. 083518 (2007).
- C. Allain, F. Schmidt, R. Lartia, G. Bordeau, C. Fiorini-Debuisschert, F. Charra, P. Tauc, MP Teulade-Fichou, « Vinyl-pyridinium Triphenylamines: novel far-red emitters with high photostability and two-photon absorption properties for staining DNA”, ChemBioChem 8 (4), 424-433 (2007).
- G. Schull , L. Douillard, C. Fiorini-Debuisschert, et al., Selectivity of single molecule dynamics in 2D molecular sieves, Adv. Materials,18(22), 2954 (2006).
- G. Schull , L. Douillard, C. Fiorini-Debuisschert, F Mathevet, D. Kreher, AJ Attias, Single molecule dynamics in a self-assembled 2D molecular sieve, Nanolett., 6(7) 1360 (2006)
- C. Cocoyer, L Rocha, L Sicot, C. Fiorini-Debuisschert et al., Implementation of submicrometric periodic surface structures : toxards improvement of organic solar cell performances , Appl. Phys Lett, 88(13), Art. No. 133108 (2006).
- JT Zoueu, C. Fiorini-Debuisschert, F. Charra et al., Transient second harmonic generation in a cyanine liquid dye solution, Chem Phys Lett., 419 (4-6), 454, (2006).
- C. Hubert, C. Fiorini-Debuisschert, I Hassiaoui et al., Emission properties of an organic light emitting diode patterned by a photoinduced autostructuration process, Appl. Phys Lett, 87 (19), 191105 (2005).
- C. Hubert, C. Fiorini-Debuisschert, P. Raimond, JM Nunzi, JJ Simon, L. Escoubas, Spontaneous photoinduced strcuturation of the surface of azobenzene polymer films by the molecular migration effect, Nonlinear Opt., Quant. Opt., Optics conceps in modern opt., 31 (1-4), 221, (2004).
- M Marcaccio, JA McCleverty, W. Akemann, C.Fiorini, et al., Photoinduced charge separation in molybdenum-monostryril-ferrocenyl-stilbene, J. Photochem Photobiol A 163 (3), 413 (2004)
- C. Hubert, C. Fiorini-Debuisschert, I Maurin et al., Spontaneous patterning of hexagonal strcutures in an azo-polymer using light-controlled mass transport, Adv Mater, 14(10), 729 (2002).
- N. Sertova, I. Petkov, C. Fiorini et al., Photoinduced surface relief grating formation in polymers doped with bis-azodyes, Mol. Cryst. Liq Cryst, 374, 77 (2002).
- Apostoluk, A; Chapron, D; Gadret, G; Sahraoui, B; Nunzi, JM; Fiorini-Debuisschert, C; Raimond, P Quasi-phase-matched gratings printed by all-optical poling in polymer films, Optics Lett., Volume: 27, Issue: 22, Pages: 2028-2030 (2002).
- L. Rocha, V. Dumarcher, C. Denis, C. Fiorini et al., Laser emission in periodically modulated polymer films, J Appl Phys, 89 (5), 3067, (2001).
- V. Dumarcher, L. Rocha, C. Denis, C. Fiorini et al., Polymer thin film distributed feedback tunable lasers, J Opt A- Pure Appl Opt, 4, 279 (2000).
- L. Sicot, C. Fiorini, A. Lorin et al., Improvement of the photovoltaic properties of polythiophene based cells, Sol Energ Mat Sol C, 63 (1), 49 (2000).
- K.P. Kretsch, W.J. Blau, V. Dumarcher, C. Fiorini et al., Distributed feedback laser action from polymeric waveguides doped with oligo phenylene vinylene model compounds, Appl. Phys Lett, 76 (16), 2149 (2000).
- Malaun, M; Kowallick, R; McDonagh, AM; Marcaccio, M; Paul, RL; Asselberghs, I; Clays, K; Persoons, A; Bildstein, B; Fiorini, C, Nunzi, JM; Ward, MD; McCleverty, JA Donor-acceptor complexes incorporating ferrocenes: spectroelectrochemical characterisation, quadratic hyperpolarisabilities and the effects of oxidising and reducing agents, JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, Issue: 20, Pages: 3025-3038 (2001).
- B. Paci, C. Schmidt, C. Fiorini, et al., Nonlinear optical properties of push-pull stilbene based on a strong carbocation acceptor moiety, J. Chem Phys, 111 (16), 7486 (1999).
- C. Arbez-Gindre, CG Screttas, C. Fiorni et al., Organolithium reagents bearing nonlinear optical chromophores. Syntheis of triarylmethane dyes, Tetrahedron Lett 40(41), 7413 (1999).
Brevets
- C. Fiorini-Debuisschert, F. Charra, L. Douillard, «Sonde active pour la microscopie optique en champ proche et son procédé de fabrication », Brevet FR12 51495 (2012).
- F. Charra, C. Fiorini-Debuisschert, R. Bachelot (UT Troyes), « Laser plasmonique et son procédé de fabrication », Brevet FR11 52615 (2011).
- C. Allain, MP Teulade Fichou, C. Fiorini-Debuisschert, F Charra, « Nouveaux dérivés de la triphenylamine utiles comme fluorophores en biologie notamment pour la microscopiebiphotonique», brevet FR06 54837 (2006).
- G. Schull , L. Douillard, C. Fiorini-Debuisschert, F Mathevet, D. Kreher, AJ Attias, “Procédé de traitement d’un fluide à l’aide d’un réseau auto-organisé adsorbé sur une surface”, Brevet FR0602760 ( 2006).
- C. Fiorini-Debuisschert, V Simic, O. Vigneau, P Lebarny, « Capteur chimique tandem hautement sélectif et procédé de détection utilisant ce capteur », brevet 04-01395 (2004).
- C. Hubert, C. Fiorini-Debuisschert, JM Nunzi, P Raimond, « Procédé de fabrication de structures périodiques bi-dimensionnelles auto-organisées, en milieu polymère » , brevet WO2005105662 (2005).
- C. Sentein, C. Fiorini, A. Lorin et J.M. Nunzi « Dispositif semiconducteur en polymère comportant au moins une fonction redresseuse et procédé de fabrication d’un tel dispositif », brevet 97 01485 (1997).
- C.Fiorini, F.Charra, J.M.Nunzi, P. Raimond et A. Lorin « Procédé de fabrication de structures en polymères organiques, transparentes, auto-organisées pour la conversion de fréquence optique », brevet 9503616 (1995).
Enseignement
1999-2004 : Option du DEA Laser et Matière, conjoint Paris VI et XI (resp. Ch Flytzanis)
“Matériaux organiques pour l’optique non-linéaire”.