Logo CEA
Recherche

Celine FIORINI

IRAMIS/DIR – Adjointe scientifique au Directeur de l’Institut IRAMIS

Service de Physique de l’État Condensé (SPEC, UMR 3680)

Laboratoire d’Électronique et nanoPhotonique Organique (LEPO)

Fonctions

  • Chercheur en nanoPhotonique (ORCID),
  • Adjointe à la Direction de l’Institu IRAMIS (2023 – )
  • Adjointe à la Direction du SPEC (2014 – 2023)
  • Coordinatrice du LabEx NanoSaclay (http://www.nanosaclay.fr/) (2019 – 2023)
  • Expert Senior CEA
  • Membre du comité de rédaction de Photoniques, la revue de la SFO
  • Présidente du Club SFO « HORIZONs de l’Optique« 

Sujets de recherche

  • Optique et nanophotonique non-linéaire en milieu organique (fluorescence, absorption multiphotonique, conversion de fréquence …)
  • Nano-antennes optiques et plasmonique moléculaire
  • Microstructuration de polymères par voie optique
  • Étude de l’organisation de la matière à différentes échelles par des techniques conjointes de spectroscopie et de microscopie à sonde locale (STM, AFM)
  • Applications : marquage de l’ADN, optimisation de composants optoélectroniques (cellules solaires plastiques, diodes organiques électroluminescentes, capteurs chimiques).

Cursus

2004-

Chercheur CEA,Direction des Sciences de la Matière / DRECAM/SPCSI puis IRAMIS/SPEC/LEPO

1995-2004

Chercheur CEA, Direction de la Recherche Technologique / Laboratoire Composants Organiques

2009

Habilitation à Diriger des Recherches (Université Paris VI-Jussieu) – « Contrôle optique de l’organisation de matériaux moléculaires : de l’échelle microscopique à la manipulation de molécules individuelles« 

1992–1995

Thèse en Sciences Physiques, optique et photonique (Paris XI-Orsay), CEA Saclay (DTA/DEIN)
« Étude des non-linéarités du second ordre induites par voie optique, application à l’orientation optique de molécules organiques. »

1989 – 1992

École Supérieure d’Optique , Orsay (now IOGS)

Publications scientifiques

~100 publications dans des revues à comité de lecture, Hirsh factor=35

Publications dans la base HAL – Open access

  1. Ge, D., Marguet, S., Issa, A., S. Jradi, H. Nguyen, M. Nahra, J. Béal, R. Deturche, H. Chen, S. Blaize, J. Plain, C. Fiorini, L. Douillard, O. Soppera, Q. Dinh Xuan, C. Dang, X. Yang, T. Xu, B. Wei, X. Wei Sun, C. Couteau, and R. Bachelot, Hybrid plasmonic nano-emitters with controlled single quantum emitter positioning on the local excitation field, Nature Commun. 11, 3414 (2020).
  2. F. Kameche, W. Heni, S. Telitel, D. Ge, L. Vidal, F. Dumur, D. Gigmes, J. Lalevée, S. Marguet, L. Douillard, C. Fiorini-Debuisschert, R. Bachelot, O. Soppera, Plasmon-triggered living photopolymerization for elaboration of hybrid polymer/metal nanoparticles, Materials Today (2020).
  3. N. Kalashnyk, M. Jaouen, C. Fiorini-Debuisschert, L. Douillard, AJ Attias, and F Charra, Electronic effects of the Bernal stacking of graphite on self-assembled aromatic adsorbates, Chem Comm 54, 9607 (2018).
  4. Molinaro C, Marguet S, Douillard L, Charra F and Fiorini-Debuisschert C From plasmon-induced luminescence enhancement in gold nanorods to plasmon-induced luminescence turn-off: a way to control reshaping Phys Chem Chem Phys 20, 12295 (2018). DOI: 10.1039/c8cp00867a
  5. Brigita Rožič,Jérôme Fresnais, Celine Molinaro,Joseph Calixte,Shivakumar Umadevi, Stephanie Lau-Truong,Nordin Felidj, Tobias Kraus,Fabrice Charra, Vincent Dupuis,Torsten Hegmann, Celine Fiorini-Debuisschert, Bruno Gallas and Emmanuelle Lacaze, Oriented Gold Nanorods and Gold Nanorod Chains within Smectic Liquid Crystal Topological Defects, ACS Nano, DOI: 10.1021/acsnano.7b01132, (2017).
  6. Sylvain Le Liepvre,Ping Du,David Kreher,Fabrice Mathevet, André-Jean Attias, Céline Fiorini-Debuisschert, Ludovic Douillard,and Fabrice Charra, Fluorescent Self-Assembled Molecular Monolayer on Graphene, ACS Photonics , DOI: 10.1021/acsphotonics.6b00793, (2016)
  7. Molinaro, C ; Yara El Harfouch, Etienne Palleau, Fabien Eloi, Sylvie Marguet, Ludovic Douillard, Fabrice Charra, Céline Fiorini-Debuisschert, Two-Photon Luminescence of Single Colloidal Gold NanoRods: Revealing the Origin of Plasmon Relaxation in Small Nanocrystals, J. PHYS CHEM C, DOI 10.1021/acs.jpcc.6b07498, (2016)
  8. Sghaier, T; Le Liepvre, S; Fiorini, C; Douillard, L; Charra, F, Optical absorption signature of a self-assembled dye monolayer on graphene, BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 7, 862 (2016). doi:10.3762/bjnano.7.78
  9. Alexis Depauw, Elena Dossi, Naresh Kumar, Céline Fiorini-Debuisschert, Gilles Huberfeld, Minh-Huong Ha-Thi, Nathalie Rouach and Isabelle Leray, A highly selective potassium sensor for the detection of potassium in living tissues, CHEMISTRY – A EUROPEAN JOURNAL, 22, 14902, DOI : 10.1002/chem.201602209, (2016)
  10. Dumat, B; Faurel-Paul, E; Fornarelli, P; Saettel, N; Metge, G; Fiorini-Debuisschert, C ; Charra, F; Mahuteau-Betzer, F; Teulade-Fichou, MP, Influence of the oxazole ring connection on the fluorescence of oxazoyl-triphenylamine biphotonic DNA probes, ORGANIC & BIOMOLECULAR CHEMISTRY, 14(1), 358, (2016). DOI: 10.1039/c5ob02225h
  11. Adrien Faucon, Thomas Maldiney, Olivier Clément, Philippe Hulin, Steven Nedellec, Myriam Robard, Nicolas Gautier, Evelien De Meulenaere, Koen Clays, Tomas Orlando, Alessandro Lascialfari, Céline Fiorini-Debuisschert, Jérôme Fresnais and Eléna Ishow, Highly cohesive dual nanoassemblies for complementary multiscale bioimaging, J. Mater. Chem. B, 2, 7747-7755 (2014)
  12. Bellec, A; Arrigoni, C; Douillard, L; Fiorini-Debuisschert, C; Mathevet, F; Kreher, D; Attias, AJ; Charra, F – Formation of hydroxyl-functionalized stilbenoid molecular sieves at the liquid/solid interface on top of a 1-decanol monolayer – Nanotechnology, Volume: 25, Issue: 43, Article Number: 435604, DOI: 10.1088/0957-4484/25/43/435604, (2014)
  13. Du, P; Jaouen, M; Bocheux, A; Bourgogne, C; Han, Z; Bouchiat, V; Kreher, D; Mathevet, F; Fiorini-Debuisschert, C; Charra, F; Attias, AJ –Surface-Confined Self-Assembled Janus Tectons: A Versatile Platform towards the Noncovalent Functionalization of Graphene – ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Volume: 53, Issue: 38, Pages: 10060-10066, DOI: 10.1002/anie.201403572, (2014)
  14. Hammerer, F; Garcia, G; Chen, S; Poyer, F; Achelle, S; Fiorini-Debuisschert,C; Teuade-Fichou, MP; Maillard, P, Synthesis and Characterization of Glycoconjugated Porphyrin Triphenylamine Hybrids for Targeted Two-Photon Photodynamic Therapy, J. Org. Chem, Volume: 79, Issue: 3, Pages: 1406-1417, DOI: 10.1021/jo402658h, (2014)
  15. Zhou, X; Deeb, C; Vincent, R; Lerond, T; Adam, PM; Plain, J; Wiederrecht, GP; Charra, F; Fiorini, C; des Francs, GC; Soppera, O; Bachelot, R – Polarization-dependent fluorescence from an anisotropic gold/polymer hybrid nano-emitter– Appl. Phys Lett, Volume: 104, Issue: 2, Article Number: 023114, DOI: 10.1063/1.4861898, (2014).
  16. Dumat, B; Bordeau, G; Faurel-Paul, E; Mahuteau-Betzer, F; Saettel, N; Metge, G; Fiorini-Debuisschert, C; Charra, F; Teulade-Fichou, MP – Switches on the Two-Photon Efficiency of an Ultrabright Triphenylamine Fluorescent Probe Specific of AT Regions – J. Am. Chem. Soc, Volume: 135, Issue: 34, Pages: 12697-12706, DOI: 10.1021/ja404422z, (2013).
  17. Bleger, D; Bocheux, A; Kreher, D; Mathevet, F; Attias, AJ ; Metge, G; Douillard, L; Fiorini-Debuisschert, C; Charra, F – An optimized alkyl chain-based binding motif for 2D self-assembly: a comprehensive crystallographic approach – NanoScale, Volume: 5, Issue: 4, Pages: 1452-1455, DOI: 10.1039/c2nr33509c (2013).
  18. Dumat, B; Bordeau, G; Aranda, AI; Mahuteau-Betzer, F; El Harfouch, Y ; Metge, G; Charra, F; Fiorini-Debuisschert, C; Teulade-Fichou, MP , Vinyl-triphenylamine dyes, a new family of switchable fluorescent probes for targeted two-photon cellular imaging: from DNA to protein labeling – Org. and Biomolec. Chem.- Volume: 10, Issue: 30, Pages: 6054-6061, DOI: 10.1039/c2ob25515d (2012).
  19. Bocheux, A; Tahar-Djebbar, I; Fiorini-Debuisschert, C; Douillard, L; Mathevet, F; Attias, AJ; Charra, F , Self-Templating Polythiophene Derivatives: Electronic Decoupling of Conjugated Strands through Staggered Packing –Langmuir -Volume: 27, Issue: 16, Pages: 10251-10255, DOI: 10.1021/la201743d (2011).
  20. Dumat, B; Bordeau, G; Faurel-Paul, E; Mahuteau-Betzer, F; Saettel, N; Bombled, M; Metge, G; Charra, F; Fiorini-Debuisschert, C; Teulade-Fichou, MP, N-phenyl-carbazole-based two-photon fluorescent probes: Strong sequence dependence of the duplex vs quadruplex selectivity –Biochimie -Volume: 93, Issue: 8, Pages: 1209-1218, DOI: 10.1016/j.biochi.2011.05.035 (2011).
  21. Bellec, A; Arrigoni, C; Schull, G; Douillard, L; Fiorini-Debuisschert, C; Mathevet, F; Kreher, D; Attias, AJ; Charra, F, Solution-growth kinetics and thermodynamics of nanoporous self-assembled molecular monolayers, J. Chem Phys, Volume: 134, Issue: 12, Article Number: 124702, DOI: 10.1063/1.3569132, (2011)
  22. Bleger, D; Mathevet, F; Kreher, D; Attias, AJ; Bocheux, A; Latil, S; Douillard, L; Fiorini-Debuisschert, C ; Charra, F, Janus-Like 3D Tectons: Self-Assembled 2D Arrays of Functional Units at a Defined Distance from the Substrate – ANGEWANDTE CHEMIE-INTERNATIONAL EDITION -Volume: 50, Issue: 29, Pages: 6562-6566, DOI: 10.1002/anie.201008212 (2011).
  23. Fiorini, C; Charra, F, Self-assembly: mastering photonic processes at nanoscale – OPTO-ELECTRONICS REVIEW, Volume: 18, Issue: 4, Pages: 376-383, DOI: 10.2478/s11772-010-0046-3 (2010).
  24. Arrigoni, C; Schull, G; Bleger, D; Douillard, L; Fiorini-Debuisschert, C; Mathevet, F; Kreher, D; Attias, AJ; Charra, F, Structure and Epitaxial Registry on Graphite of a Series of Nanoporous Self-Assembled Molecular Monolayers – J. Phys Chem Lett, Volume: 1, Issue: 1, Pages: 190-194, DOI: 10.1021/jz900146f (2010).
  25. Bordeau, G; Lartia, R; Metge, G; Fiorini-Debuisschert, C; Charra, F; Teulade-Fichou, MP, Trinaphthylamines as Robust Organic Materials for Two-Photon-Induced Fluorescence – J. Am. Chem. Soc, Volume: 130, Issue: 50, Pages: 16836-+, DOI: 10.1021/ja8055112 (2008)
  26. Berline, I; Fiorini-Debuisschert, C; Royal, C; Douillard, L; Charra, F, Molecular second harmonic generation induced at a metallic tip – J. Appl. Phys. -Volume: 104, Issue: 10, Article Number: 103113, DOI: 10.1063/1.3028265 (2008).
  27. Ishow, E; Brosseau, A; Clavier, G; Nakatani, K; Tauc, P; Fiorini-Debuisschert, C; Neveu, S; Sandre, O; Leaustic, A – Multicolor Emission of Small Molecule-Based Amorphous Thin Films and Nanoparticles with a Single Excitation Wavelength, Chem. Mat., Volume: 20, Issue: 21, Pages: 6597-6599, DOI: 10.1021/cm802264c (2008).
  28. Schull, G; Ness, H; Douillard, L; Fiorini-Debuisschert, C; Charra, F; Mathevet, F; Kreher, D (Kreher, David); Attiast, AJ, Atom substitution for marking and motion tracking of individual molecules by scanning tunneling microscopy, J. Phys Chem C, Volume: 112, Issue: 36, Pages: 14058-14063, DOI: 10.1021/jp8030013 (2008)
  29. Lartia, R; Allain, C; Bordeau, G; Schmidt, F; Fiorini-Debuisschert, C; Charra, F; Teulade-Fichou, MP, Synthetic strategies to derivatizable triphenylamines displaying high two-photon absorption, J. Org. Chem., Volume: 73, Issue: 5, Pages: 1732-1744, DOI: 10.1021/jo702002y (2008)
  30. D. Bleger, D. Kreher, F. Mathevet, AJ Attias, G. Schull, A. Huard, L Douillard, C. Fiorini-Debuisschert, F. Charra, A surface-activated non-covalent bonding for rational design of hierarchical molecular self-assemblies, Andegewandte Chem. Int. Ed., 46, 7404, (2007).
  31. C. Hubert , Fiorini-Debuisschert , L Rocha, et al., Spontaneous photoinduced patterning of azo-dye polymer films : the facts, J Opt Soc Am. B, 24 (8): 1839-1846 (2007).
  32. L. Douillard, F. Charra, C. Fiorini et al., Optical properties of metal nanoparticles as probed by photoemission electron microscopy, J. Appl. Phys., 101 (8) art. 083518 (2007).
  33. C. Allain, F. Schmidt, R. Lartia, G. Bordeau, C. Fiorini-Debuisschert, F. Charra, P. Tauc, MP Teulade-Fichou, « Vinyl-pyridinium Triphenylamines: novel far-red emitters with high photostability and two-photon absorption properties for staining DNA”, ChemBioChem 8 (4), 424-433 (2007).
  34. G. Schull , L. Douillard, C. Fiorini-Debuisschert, et al., Selectivity of single molecule dynamics in 2D molecular sieves, Adv. Materials,18(22), 2954 (2006).
  35. G. Schull , L. Douillard, C. Fiorini-Debuisschert, F Mathevet, D. Kreher, AJ Attias, Single molecule dynamics in a self-assembled 2D molecular sieve, Nanolett., 6(7) 1360 (2006)
  36. C. Cocoyer, L Rocha, L Sicot, C. Fiorini-Debuisschert et al., Implementation of submicrometric periodic surface structures : toxards improvement of organic solar cell performances , Appl. Phys Lett, 88(13), Art. No. 133108 (2006).
  37. JT Zoueu, C. Fiorini-Debuisschert, F. Charra et al., Transient second harmonic generation in a cyanine liquid dye solution, Chem Phys Lett., 419 (4-6), 454, (2006).
  38. C. Hubert, C. Fiorini-Debuisschert, I Hassiaoui et al., Emission properties of an organic light emitting diode patterned by a photoinduced autostructuration process, Appl. Phys Lett, 87 (19), 191105 (2005).
  39. C. Hubert, C. Fiorini-Debuisschert, P. Raimond, JM Nunzi, JJ Simon, L. Escoubas, Spontaneous photoinduced strcuturation of the surface of azobenzene polymer films by the molecular migration effect, Nonlinear Opt., Quant. Opt., Optics conceps in modern opt., 31 (1-4), 221, (2004).
  40. M Marcaccio, JA McCleverty, W. Akemann, C.Fiorini, et al., Photoinduced charge separation in molybdenum-monostryril-ferrocenyl-stilbene, J. Photochem Photobiol A 163 (3), 413 (2004)
  41. C. Hubert, C. Fiorini-Debuisschert, I Maurin et al., Spontaneous patterning of hexagonal strcutures in an azo-polymer using light-controlled mass transport, Adv Mater, 14(10), 729 (2002).
  42. N. Sertova, I. Petkov, C. Fiorini et al., Photoinduced surface relief grating formation in polymers doped with bis-azodyes, Mol. Cryst. Liq Cryst, 374, 77 (2002).
  43. Apostoluk, A; Chapron, D; Gadret, G; Sahraoui, B; Nunzi, JM; Fiorini-Debuisschert, C; Raimond, P Quasi-phase-matched gratings printed by all-optical poling in polymer films, Optics Lett., Volume: 27, Issue: 22, Pages: 2028-2030 (2002).
  44. L. Rocha, V. Dumarcher, C. Denis, C. Fiorini et al., Laser emission in periodically modulated polymer films, J Appl Phys, 89 (5), 3067, (2001).
  45. V. Dumarcher, L. Rocha, C. Denis, C. Fiorini et al., Polymer thin film distributed feedback tunable lasers, J Opt A- Pure Appl Opt, 4, 279 (2000).
  46. L. Sicot, C. Fiorini, A. Lorin et al., Improvement of the photovoltaic properties of polythiophene based cells, Sol Energ Mat Sol C, 63 (1), 49 (2000).
  47. K.P. Kretsch, W.J. Blau, V. Dumarcher, C. Fiorini et al., Distributed feedback laser action from polymeric waveguides doped with oligo phenylene vinylene model compounds, Appl. Phys Lett, 76 (16), 2149 (2000).
  48. Malaun, M; Kowallick, R; McDonagh, AM; Marcaccio, M; Paul, RL; Asselberghs, I; Clays, K; Persoons, A; Bildstein, B; Fiorini, C, Nunzi, JM; Ward, MD; McCleverty, JA Donor-acceptor complexes incorporating ferrocenes: spectroelectrochemical characterisation, quadratic hyperpolarisabilities and the effects of oxidising and reducing agents, JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, Issue: 20, Pages: 3025-3038 (2001).
  49. B. Paci, C. Schmidt, C. Fiorini, et al., Nonlinear optical properties of push-pull stilbene based on a strong carbocation acceptor moiety, J. Chem Phys, 111 (16), 7486 (1999).
  50. C. Arbez-Gindre, CG Screttas, C. Fiorni et al., Organolithium reagents bearing nonlinear optical chromophores. Syntheis of triarylmethane dyes, Tetrahedron Lett 40(41), 7413 (1999).

Brevets

  1. C. Fiorini-Debuisschert, F. Charra, L. Douillard, «Sonde active pour la microscopie optique en champ proche et son procédé de fabrication », Brevet FR12 51495 (2012).
  2. F. Charra, C. Fiorini-Debuisschert, R. Bachelot (UT Troyes), « Laser plasmonique et son procédé de fabrication », Brevet FR11 52615 (2011).
  3. C. Allain, MP Teulade Fichou, C. Fiorini-Debuisschert, F Charra, « Nouveaux dérivés de la triphenylamine utiles comme fluorophores en biologie notamment pour la microscopiebiphotonique», brevet FR06 54837 (2006).
  4. G. Schull , L. Douillard, C. Fiorini-Debuisschert, F Mathevet, D. Kreher, AJ Attias, “Procédé de traitement d’un fluide à l’aide d’un réseau auto-organisé adsorbé sur une surface”, Brevet FR0602760 ( 2006).
  5. C. Fiorini-Debuisschert, V Simic, O. Vigneau, P Lebarny, « Capteur chimique tandem hautement sélectif et procédé de détection utilisant ce capteur », brevet 04-01395 (2004).
  6. C. Hubert, C. Fiorini-Debuisschert, JM Nunzi, P Raimond, « Procédé de fabrication de structures périodiques bi-dimensionnelles auto-organisées, en milieu polymère » , brevet WO2005105662 (2005).
  7. C. Sentein, C. Fiorini, A. Lorin et J.M. Nunzi « Dispositif semiconducteur en polymère comportant au moins une fonction redresseuse et procédé de fabrication d’un tel dispositif », brevet 97 01485 (1997).
  8. C.Fiorini, F.Charra, J.M.Nunzi, P. Raimond et A. Lorin « Procédé de fabrication de structures en polymères organiques, transparentes, auto-organisées pour la conversion de fréquence optique », brevet 9503616 (1995).

Enseignement

1999-2004 : Option du DEA Laser et Matière, conjoint Paris VI et XI (resp. Ch Flytzanis)
“Matériaux organiques pour l’optique non-linéaire”.