Ludovic DOUILLARD

Fonction

Chercheur au Commissariat à l’énergie atomique et aux énergies alternatives CEA

CEA Orme des Merisiers, Bât. 774

Direction de la Recherche Fondamentale – DRF

Institut rayonnement matière de Saclay – IRAMIS

Service de physique de l’état condensé – SPEC

Laboratoire d’électronique et nanophotonique organique – LEPO

Sujets de recherche

Physique des surfaces

– Structuration planaire par voie ascendante  (échelle nano., mémoire HdR)

– Reconstructions de surface

– Instabilités cinétiques de croissance

– Interaction photon matière, optique sub longueur d’onde

– Architectures supramoléculaires bidimensionnels

– Plasmonique

CV

Cursus ————————————————————————————————

Parcours professionnel ——————————————————————————

Lab. nanostructures autoorganisées (1997 – 2004) – Animateur H.-J. Ernst CEA
– Phénomènes d’autoorganisation hors d’équilibre, instabilités cinétiques de croissance

Lab. surfaces et interfaces des matériaux avancés (1995 – 97) – Animateur P. Soukiassian Paris XI
– Physique des surfaces de semiconducteurs
– Séjour à l’Université de Madison, Wisconsin, États – Unis

Enseignement —————————————————————————————

2025 – … M2 Nano-optics and Nanophotonics NANO-PHOT de l’Université de Technologie de Troyes, 2hrs/an

2019 – … M2 Matériaux pour l’énergie et les transports MET, Univ. Paris Saclay – Microscopies Champ Proche & Spectrométries de surface, 10 hrs/an

2019 – … Institut d’Optique Graduate School ParisTech Palaiseau – Microscopies Champ Proche, 3 hrs/an

2004 – … M2 Couches Minces & Management Industriel MAMI, Univ. Paris Saclay – Spectrométries de surface, 22 hrs/an

1997 – 2003 M2 Instrumentation et Méthodes Physico-Chimiques d’Analyse IMPCA, Univ. Paris Sud & CEA INSTN – Spectrométries de surface, 25 hrs/an

1999 – 2003 Société française du vide (SFV) Formation pour adultes, niveaux technicien & ingénieur

Publications scientifiques

Publications HAL-CEA

Publications (sélection > année 2000)

Spectral approach to electron emission analysis from heterogenous surfaces J. Ludwick, et al. Phys. Rev. Appl. 25 (2026) 044070 /10.1103/p1lh-79xp

Exploring plasmonic hotspots of Au tilted nanocolumns and their application to the uracil detection by surface-enhanced Raman scattering. G. Barbillon, et al. Appl. Surf. Sci. 709 (2025) 163800 /10.1016/j.apsusc.2025.163800

Interplay of deposition kinetics with metal diffusion in MoO₃-Cu heterojunctions E. Torretti, et al. Appl. Surf. Sci. 695 (2025) 162680 /10.1016/j.apsusc.2025.162680

Surface structure of Sn doped β-Ga₂O₃(010) studied by quantitative low energy electron diffraction A. Pancotti, et al. Surf. Sci. 753 (2025) 122653 /10.1016/j.susc.2024.122653

Spatial distribution of the photopolymerization induced by localized surface plasmons: Impact of the morphology of the Au nanoparticles. A. Khitous, et al. J. Phys. Chem. C 128 (2024) 13097 /10.1021/acs.jpcc.4c03148

Approaches for positioning the active medium in hybrid nanoplasmonics. Focus on plasmon-assisted photopolymerization M. Chen, et al. ACS Photonics 11 (2024) 3933 /10.1021/acsphotonics.4c00868

Optical characterization of a single molecule complete spatial orientation using intra-molecular triplet-triplet absorption R. Trojanowicz, et al. Phys. Chem. Chem. Phys. 26 (2024) 16350 /10.1039/D4CP00867G

Probing the optical near-field R. Bachelot, L. Douillard Springer Series in Optical Sciences SSOS 244 Springer Advances in Near-Field Optics Hardcover ISBN978-3-031-34741-2, Online ISBN978-3-031-34742-9, 16 September 2023

Highlight on commercial SERS substrates and on optimized nanorough large-area SERS-based sensors: A Raman study M. Rahmani, et al. Appl. NanoSci. 14 (2023) 203 /10.1007/s13204-023-02972-6

Quantitative PEEM and Raman Study of Nanorough Au SERS-Active Substrates for Molecular Sensing Applications  P. Taugeron, et al. ACS Appl. Nano Mater. 6 (2023) 11135-11143

Patterning gold nanorod assemblies by deep-UV lithography C. Jégat, et al. J. Phys. Chem. C 126, 32, (2022) 13729

Probing Plasmon Induced Chemical Mechanisms by Free Radical NanoPhotopolymerization F. Kameche, et al. J. Phys. Chem. C 125 (2021) 16 8719–8731

La microscopie de photoémission d’électrons, un outil multidimensionnel pour l’optique champ proche A. Losquin, L. Douillard Photoniques 102 (2020) 35-38

Hybrid plasmonic nano-emitters with controlled single quantum emitter positioning on the local excitation field D. Ge, et al. Nature Comm. 11 (2020) 3414

Plasmon-triggered living photopolymerization for elaboration of hybrid polymer/metal nanoparticles F. Kameche, et al. Materials Today (2020)

Plasmonics of regular shape particles, a simple group theory approach S. Mitiche, S. Marguet, F. Charra, L. Douillard Nano Research (2020) //rdcu.be/b3Col

Nanoscale Imaging of Ultrafast Light Coupling to Self-Organized Nanostructures A. Abou Saleh, et al. ACS Photonics 6 (2019) 2287-2294

All semiconductor enhanced high-harmonic generation from an isolated nanostructure D. Franz, et al. Sci. Rep. 9 (2019) 5663

Electronic effects of the Bernal stacking of graphite on self-assembled aromatic adsorbates N. Kalashnyk, et al. Chem. Comm. 54 (2018) 9607–9610

From plasmon-induced luminescence enhancement in gold nanorods to plasmon-induced luminescence turn-off: a way to control reshaping C. Molinaro, et al. Phys. Chem. Chem. Phys. 20 (2018) 12295

Near-Field Localization of Single Au Cubes, a Predictive Group Theory Scheme S. Mitiche, S. Marguet, F. Charra, L. Douillard Journal of Physical Chemistry C 121 (2017) 4517–4523

Direct graphene growth on transitional metal with solid carbon source and its converting into graphene/transitional metal oxide heterostructure J. Park, et al. Carbon 116 (2016) 303-309

Local investigation of the emissive properties of LaB6-ZrB2 eutectics M.-H. Berger, et al. J. of Mat. Sci. 52 (2017) 5537-5543

Fluorescent self-assembled molecular monolayer on graphene S. Le Liepvre, et al. ACS Photonics 3 (2016) 2291-2296 /10.1021/acsphotonics.6b00793

Plasmonics of opal surface: a combined near- and far-field approach C. Lethiec, et al. J. Phys. Chem. C 120 (2016) 19308−19315 DOI: 10.1021/acs.jpcc.6b05718

Two-Photon Luminescence of Single Colloidal Gold Nanorods: Revealing the Origin of Plasmon Relaxation in Small Nanocrystals C. Molinaro, et al. J. Phys. Chem. C 120 (2016) 23136–23143

Optical absorption signature of a self-assembled dye monolayer on graphene T. Sghaier, et al. Beilstein J. Nanotechnol. 7 (2016) 862–868

High resolution scanning near field mapping of enhancement on SERS substrates: comparison with photoemission electron microscopy C. Awada, et al. Phys. Chem. Chem. Phys. 18 (2016) 9405-9411 /10.1039/C5CP08015K

Probing plasmonic hot spots on single gold nanowires using combined near-field techniques
P. Hsia, et al. Conference: SPIE Optics and Photonics Conference on Plasmonics, Metallic Nanostructures and their Optical Properties XIII San Diego, CA Date: AUG 09-13, 2015 SPIE PLASMONICS: METALLIC NANOSTRUCTURES AND THEIR OPTICAL PROPERTIES XIII Proceedings of SPIE Volume: 9547 95470F 2015

STM-induced phase change and photon emission in thiol-based self-assembled monolayers on gold (111) M. Jaouen, et al. Nonlinear Optics Quantum Optics 46.2-4 (2015) 299-308

Formation of hydroxyl-functionalized stilbenoid molecular sieves at the liquid/solid interface on top of a 1-decanol monolayer A. Bellec, et al. Nanotechnology 25 (2014) 435604

Photoemission electron microscopy, a tool for plasmonics L. Douillard, F. Charra J. of elect. spect. rel. phenom. 189 (2013) 24

An optimized alkyl chain-based binding motif for 2D self-assembly: a comprehensive crystallographic approach D. Bléger, et al. Nanoscale 5 (2013) 1452

Microscopie à haute résolution des champs plasmoniques par microscopie tunnel à balayage de sonde et par microscopie de photoémission multiphotonique L. Douillard, F. Charra
Comptes Rendus Physique 13 (2012) 815

Fractoluminescence characterization of the energy dissipated during fast fracture of glass.
G. Pallares, et al. Eur. Phys. Lett. 99 (2012) 28003

Selective excitation of plasmon resonances of single Au triangles by polarization dependent light excitation C. Awada, et al. J. of Phys. Chem. C 116 (2012) 14591-14598

Loss mechanisms of surface plasmon polaritons propagating on a smooth polycrystalline Cu surface. Lee, Hyun Seok, et al. Optics Express 20 (2012) 8974-8981

Experimental study of hot spots in gold/glass nanocomposite films by photoemission electron microscopy. C. Awada, et al. Phys. Rev. B 85 (2012) 045438

High-resolution mapping of plasmonic modes: photoemission and scanning tunnelling luminescence microscopies. L Douillard, F. Charra J. of Phys. D: Appl. Phys. 44 (2011) 464002

Self-Templating Polythiophene Derivatives: Electronic Decoupling of Conjugated Strands through Staggered Packing. A. Bocheux, et al. Langmuir 2011 27 (16) 10251

Solution-growth kinetics and thermodynamics of nanoporous self-assembled molecular monolayers. Charra F., et al. Journal of Chemical Physics, 134, (2011) 124702-1 124702-7

Selective excitation of individual plasmonic hotspots at the tips of single gold nanostars.
Hrelescu C., et al. Nano Letters, 11, (2011) 402-407

Structure and Epitaxial Registry on Graphite of a series of nanoporous self-assembled molecular monolayers. Arrigoni C., et al. J. of Phys. Chem. Lett. 1 (2010) 190-194

Short range plasmon resonators probed by photoemission electron microscopy. Douillard L., et al. Nano Letters, 8, (2008) 935-940

Single atom substitution for marking and motion tracking of individual molecules by scanning tunneling microscopy Douillard L., et al. J. of Phys. Chem. C 112 (2008) 14058-14063

Molecular second harmonic generation induced at a metallic tip. Berline I., et al. Journal of Applied Physics 104 (2008) 103113

Periodic positioning of multilayered [2.2] paracyclophane-based nanopillars. Bléger D., et al. Angewandte Chemie – International Edition, 47, (2008) 8412-8415

Optical properties of metal nanoparticles as probed by photoemission electron microscopy.
Douillard L., et al. Journal of Applied Physics, 101, (2007) 083518

Surface Noncovalent Bonding for Rational Design of Hierarchical Molecular Self-Assemblies.
Bléger D., et al. Angewandte Chemie International Edition, 46, (2007) 7404-7407

Single-Molecule Dynamics in a Self-Assembled 2D Molecular Sieve. Schull G., et al. Nano Letters 6 (2006) 1360-1363

Selectivity of single-molecule dynamics in a 2D molecular sieve. G. Schull, et al. Adv. Mater. 18 (2006) 2954

Spontaneous structural pattern formation at the nanometre scale in kinetically restricted homoepitaxy on vicinal surfaces. Néel N. , Maroutian T., Douillard L., Ernst H.-J. J. of Phys. Cond. Matter 15 (2003) S3227

From meandering to faceting, is step flow growth ever stable? Néel N. , Maroutian T., Douillard L., Ernst H.-J. Phys. Rev. Lett. 91 (2003) 226103

A novel method to determine the Ehrlich-Schwoebel barrier. Gerlach R., Maroutian T., Douillard L., Martinotti D., Ernst H.-J. Surf. Sci. 480 (2001) 97

Morphological instability of Cu vicinal surfaces during step flow growth. Maroutian T., Douillard L., Ernst H.-J. Phys. Rev. B. 64 (2001) 165401

Scanning tunneling microscopy evidence of background contamination-induced (2×1) ordering of the β-SiC(100) c(4×2) surface Douillard L. , et al. Appl. Surf. Sci. 166 (2000) 220

Enseignement

Université Paris Sud – Master Pro & Recherche CMMI Couches Minces & Management Industriel

•Méthodes d’analyse des surfaces – Introduction (239 Ko)

•Spectrométrie de photoélectrons – Introduction (398 Ko)

•Spectrométrie d électrons Auger – Introduction (710 Ko)

•Spectrométrie de perte d énergie des électrons – Introduction (571 Ko)

•Spectrométrie d émission d ions secondaires – Introduction (385 Ko)

•Spectrométrie par faisceau d ions – Introduction (928 Ko)

•Spectrométrie d absorption des rayons X – Introduction (355 Ko)

•Spectrometrie_d_absorption_des_rayons_X_Partie_1 (807 Ko)

•Spectrométrie d absorption des rayons X – Partie 2 (1.2 Mo)

•Diffraction d électrons lents – Partie 1 (284 Ko)

•Diffraction d électrons lents – Partie 2 (2.3 Mo)

•Microscopie à effet tunnel – Introduction (337 Ko)

•Microscopie à force atomique (1.9 Mo)

•Scanning Probe Microscopies (in English) (959 Ko)

•Références bibliographiques, acronymes spectrométries (57 Ko)

Institut d’Optique Graduate School ParisTech Palaiseau

• Techniques Champ Proche – Mapping the evanescent field at the nanometre – Near Field microscopies

Discussion GdR Or-Nano Juin 2019 Plasmonique & Electrons chauds

• Génération d’électrons chauds dans des structures métalliques : origine, définitions & principales propriétés

Divers

Mémoire HDR (PDF 13 Mo)

Soutenance HdR (9 décembre 2010)

Instabilités cinétiques de croissance, aspects expérimentaux (Cargèse 2003)

Microscopie de photoémission d’électrons, un outil pour la plasmonique Forum des microscopies à sonde locale, Hardelot, 19 Mars 2009

LDouillard_HC_EBauer_150409.pdf (E. Bauer, Dr.Hc. celebration, 15 Avril 2009)

LDouillard_UltraFastOptics_Mulheim_102013.pdf Plasmonics of single nanometric objects – Near field mapping by photoemission electron microscopy, Ultrafast Nanooptics, Mülheim an der Ruhr October 2013

Mapping the evanescent field at the nanometre – Near Field microscopies IOGS Palaiseau France 2021

Génération d’électrons chauds dans des structures métalliques : Origine, définitions & principales propriétés Discussion GdR Or-Nano Juin 2019

Coupling photons & electrons. Electron microscopy, a tool for near field optics Optique Dijon 2021

IESC Cargèse Ecole thématique Or-nano Avril 2026 Etude du champ proche optique à l’aide d’électrons