Des chercheurs de SPEC/SPHYNX, du CNRS-Université de la Sorbonne/PHENIX et du LLB/MMB publient une étude complète sur des suspensions colloïdales modèles dans un liquide ionique. Le système, constitué de nanoparticules magnétiques de type maghémites (Fe2O3) dans du nitrate d'éthylammonium, est étudié sur une large gamme de concentrations, en analysant sa structure à l'échelle nanométrique, sa thermodiffusion et sa thermoélectricité. Ces propriétés sont toutes influencées par l'organisation interfaciale des espèces à proximité de l'interface solide-liquide. L'étude ouvre une nouvelle voie pour optimiser la thermoélectricité des colloïdes pour la récupération de chaleur résiduelle.
Elle a été retenue pour illustrer la couverture de ChemEngineering Volume 4, numéro 1 (mars 2020) .
Researchers from SPEC/SPHYNX, CNRS-Sorbonne University/PHENIX and LLB/MMB have recently published a comprehensive study on model colloidal suspensions in ionic liquid. The system, consisting of maghemite magnetic nanoparticles (Fe2O3) in ethylammonium nitrate, is studied on a large concentration range, analyzing its nanostructure, thermodiffusion and thermoelectricity. These properties are all influenced by the interfacial organization of the species near the solid–liquid interface. The study has become the ‘cover story’ ChemEngineering Volume 4, Issue 1 (March 2020) , and paves a new path for tuning thermoelectricity of colloids, in the context of waste-heat harvesting.
Ferrofluids are a class of colloidal suspensions made of magnetic nanoparticles dispersed in non-magnetic media. Owing to the superparamagnetic nature of individual particles and the magnetic interactions among them, ferrofluids exhibit unique and reversible properties under an external magnetic field, making them an attractive smart material for rheological, thermal, photonic and more recently, for thermoelectro-chemical energy conversion applications. To enable such energy conversion, a ferrofluid is mixed with redox-active salts (called ‘redox couple’ made with transition metal ions in oxidized and reduced state) and placed between conducting electrodes in a device known as ‘thermocell.’ When a temperature gradient is applied, two thermoelectric phenomena take place and generate a voltage bias ΔV between the electrodes : the thermogalvanic and the thermo(electro)diffusion effects (see Fig.1, Bottom-right) . The former relies on the temperature dependent redox reactions between the redox-species (here, I- and I3-) and the electrodes while the latter is due to the thermodiffusion of charged particles and ions, similar to the Seebeck effect in solid materials. Though both effects contribute to the overall thermocell voltage bias ΔV, it has become customary to introduce Se= -ΔV/ΔT as the total Seebeck coefficient of a thermocell.
The intensity of thermodiffusion is expressed in terms of Ludwig-Soret coefficient, ST = - ∇c/∇T (see Fig.1, Top-right), where ∇c is the concentration gradient induced by a temperature gradient ∇T. For electrically neutral particles, ST is proportional to the Eastman entropy of transfer Ŝ, which is the interaction entropy between the moving particle and its surrounding molecules. In the case of electrically charged particles, an additional (thermo)electric force interferes with the particle diffusion either constructively or destructively, depending on the relative sign of the electric field and the sign of the particles’ surface charge (Zeff). The relationship between the Ludwig-Soret coefficient and the Seebeck coefficient can be determined using the Onsager reciprocal relations for heat and mass flows; and are shown to depend on three common parameters: the diffusion coefficient (Dm), the effective charge (Zeff) and the Eastman entropy of transfer (Ŝ). Such analytical description has been used successfully to reproduce the experimental observations on the thermoelectro-diffusion of charged colloidal suspensions in weak electrolytes (e.g., DNA molecules or nanoparticles dispersed in water, organic solvents, etc.) [4-6]; however, its validity is yet to be tested in strong electrolytes, for example, in room temperature ionic liquids.
Room temperature ionic liquids (RTILs) are molten salts with low melting temperature (below 100 °C). They have unique thermophysical and electrochemical properties such as reduced flammability, low vapor tension and high thermal stability. By dispersing therein magnetic nanoparticle, their bespoke application potential can be broadened to extreme environments, e.g., in electrospray thrusters for rockets or in high-vacuum seals for microelectronic device fabrications. However, the large ion concentrations in ionic liquids renders classical theories such as the Poisson–Boltzmann equation describing the formation of Debye layer at the solid-liquid interface invalid. Furthermore, the synthesis techniques developed for colloidal dispersions in weak electrolytes are revealed ineffective in RTILs. Consequently, the synthesis of ionic-liquid based colloidal dispersions (not limited to ferrofluids) was quickly recognized as a formidable challenge to both fundamental science and engineering.
Published in ChemEngineering (cover story ) in March 2020, K. Bhattacharya et al. (SPEC/SPHYNX, CNRS-Sorbonne University/PHENIX and LLB/MMB) report a systematic study on the synthesis, colloidal structure and the thermodiffusion/thermoelectric properties of an RTIL-based ferrofluid (made of citrate-coated maghemite nanoparticles dispersed in ethylammonium nitrate with Na+ counterions) for a wide range of nanoparticle volume fraction Φ. The colloidal structure was investigated using the Small Angle X-ray Scattering (SWING@SOLEIL) technique, while the solid-liquid interfacial structure; i.e., the charge composition at the nanoparticle surface, was studied via chemical titration. The organization of ethylammonium, nitrate and sodium ions close to the (originally) negatively charged particle surface was found to form layers of ions with alternating signs. This layering is believed to be at the origin of the colloidal stability in ionic liquids, dictating both the nanostructure of the dispersions and the interparticle interactions.
In parallel, the thermodiffusion coefficients (Soret coefficient ST and diffusion coefficient Dm) were measured by forced Rayleigh scattering experiments (CNRS-Sorbonne University/PHENIX, ) as a function of temperature and the nanoparticle concentration. The results were then compared to the Seebeck coefficient (Se) measured in a homemade thermocell developed at SPEC/SPHYNX. Finally, by comparing the experimental data to a theoretical model (taking in account the contributions from additional mobile ions in the RTIL), it was possible to estimate the effective charge Zeff of the nanoparticles and the Eastman entropy of transfer Ŝ.
Fig.2: a) Room temperature (normalized) Soret coefficient ST as a function of nanoparticle volume fraction Φ. The red curve is produced with a theoretical model (see  for more explanation) using Zeff = ± 55 and Ŝ/kT=6.0 K-1. b) ΔSe (nanoparticle contribution to the total Seebeck coefficient) at T = 25 °C compared to theoretically expected values with Zeff= +55 and Ŝ/kT =6.0 K-1 (blue dashed line). The dotted lines in black and magenta are produced using different combinations of Zeff and Ŝ/kT to obtain their extreme ranges of values (Zeff = +110, Ŝ/kT = 6 K-1 (black) and Zeff =+55, Ŝ/kT = 10 K-1 (magenta dotted line)).
As can be seen from Fig.2, the two independent measurements (ST and Se) lead to common values of Zeff and Ŝ i.e., Zeff = +55 and Ŝ/kT=6.0 K-1. It is interesting to note that the sign of the effective charge of the magnetic nanoparticles (inferred from the thermoelectric measurements) is positive, reversed from the initial condition in water. This results from the adsorption of EA+ cations in the first ionic layer surrounding the citrate-coated nanoparticles together with some Na+ cations, remaining from the initial step of the synthesis.
The quantitative match between the two measurements demonstrates the robustness of the present theoretical approach beyond weak electrolytes. Simultaneously, the findings also suggest that with a proper tuning of nanoparticle effective charge (the sign and the magnitude) and the Eastman entropy of transfer, one can hope to concoct ionic-liquid based ferrofluids where the inclusion of nanoparticles can effectively enhance the Seebeck coefficient.
Contact CEA: Sawako Nakamae, Groupe SPHYNX, DRF/IRAMIS/SPEC
 K. Bhattacharya, M. Sarkar, T. J. Salez, S. Nakamae, G. Demouchy, F. Cousin, E. Dubois, L. Michot, R. Perzynski and V. Peyre, Structural, thermodiffusive and thermoelectric properties of maghemite nanoparticles dispersed in ethylammonium nitrate, ChemEngineering 4, 5 (2020)
 See for example, T. J. Salez et al., Thermoelectricity and Thermodiffusion in Magnetic Nanofluids: Entropic Analysis, Entropy 20, 405 (2018) and the references within.
 S. A. Putnam and D. G. Cahill, Transport of nanoscale latex spheres in a temperature gradient, Langmuir 21, 5317 (2005)
 K. A. Eslahian and M. Maskos, Hofmeister effect in thermal field- flow fractionation of colloidal aqueous dispersions, Colloids Surf. A 413, 65 (2012)
 M. Kouyaté, et al., Thermodiffusion of citrate-coated g-Fe2O3 nanoparticles in aqueous dispersions with tuned counter-ions—Anisotropy of the Soret coefficient under magnetic field, Phys. Chem. Chem. Phys. 21, 1895 (2019)
 D. Braun and A. Libchaber, Thermal force approach to molecular evolution, Phys. Biol. 1, 1 (2004)
 See for example, G. Demouchy et al., Diffusion and thermodiffusion studies in ferrofluids with a new two-dimensional forced Rayleigh-scattering technique, J. Phys. D: Appl. Phys. 37, 1417 (2004).
• Matériaux des nouvelles technologies pour l’énergie › Conversion de l'énergie
• UMR 3680 - Service de Physique de l'Etat Condensé (SPEC)