Publications

  • Fluorophosphoniums as Lewis acids in organometallic catalysis: application to the carbonylation of β-lactones
    Chem. Commun. 2024

    M.-H. Pietraru, L. Ponsard, N. Lentz, P. Thuéry, E. Nicolas*, T. Cantat*

  • CO2/13CO2 Dynamic Exchange in the Formate Complex [(2,9-(tBu)2-phen)Cu(O2CH)] and Its Catalytic Activity in the Dehydrogenation of Formic Acid
    Organometallics 2023

    K. Phung, P. Thuéry, J.-C. Berthet*, T. Cantat*

  • Metal-Free Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with "Inverse" Frustrated Lewis Pairs
    Chem. Eur. J. 2023

    G. Durin, J.-C. Berthet, P. Thuéry, E. Nicolas, T. Cantat*

  • Catalyst-free depolymerization of polycaprolactone to silylated monoesters and iodide derivatives using iodosilanes
    Chem.Commun. 2023

    X. Liu, M. Kobylarski, J.-C. Berthet*, T. Cantat*

  • Catalytic Carbonylation of Acrylic Acid to Succinic Anhydride
    ChemCatChem 2023

    M.-H. Pietraru, N. Lentz, L. Ponsard, E. Nicolas*, T. Cantat*

  • Activation of N−O σ Bonds with Transition Metals: A Versatile Platform for Organic Synthesis and C−N Bonds Formation
    Eur. J. Org. Chem. 2023

    U. Todorovic, R. M. Romero, L. Anthore-Dalion*

  • Evaluation of acetophenone as a novel alcohol-cycloalkane bifunctional liquid organic hydrogen carrier (LOHC)
    Int. J. Hydrog. Energy 2023

    F. D'Ambra, J. Levy, P. Hajiyev, T. Cantat, G. Gébel, V. Faucheux, E. Nicolas*

  • Catalytic Methoxylation of Aryl Halides Using 13C- and 14C-Labeled CO2
    Chem. Commun. 2022

    A. Ohleier, A. Sallustrau, B. Mouhsine, F. Caillé*, D. Audisio*, T.Cantat*

  • Zirconium-catalysed hydrosilylation of esters and depolymerisation of polyester plastic waste
    Green Chem. 2022

    M. Kobylarski, L. J. Donnelly*, J.-C. Berthet, T. Cantat*

  • Alkyl Formates as Transfer Hydroalkylation Reagents and Their Use in the Conversion of Imines to Alkylamines
    Angew. Chem. Int. Ed. 2022

    E. Crochet, L. Anthore-Dalion, T. Cantat*

  • Selective Reduction of Secondary Amides to Imines Catalysed by Schwartz's Reagent
    Angew. Chem. Int. Ed. 2022

    L. J. Donnelly*, J.-C. Berthet, T. Cantat*

  • Metal-free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes
    Angew. Chem. Int. Ed. 2022

    G. Durin, A. Fontaine, J.-C. Berthet, E. Nicolas, P. Thuéry, T. Cantat*

  • Reductive depolymerization of polyesters and polycarbonates with hydroboranes by using a lanthanum(iii) tris(amide) catalyst
    Chem. Commun. 2022

    M. Kobylarski, J.-C. Berthet*, T. Cantat*

  • Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones
    Chem. Commun. 2022

    R. M. Romero, N. Thyagarajan, N. Hellou, C. Chauvier, T. Godou, L. Anthore-Dalion, T. Cantat*

  • Additive-free selective methylation of secondary amines with formic acid over a Pd/In2O3 catalyst
    Catal. Sci. Technol. 2022

    C. Genre*, I. Benaissa, T. Godou, M. Pinault, T. Cantat*

  • Uranyl(VI) Triflate as Catalyst for the Meerwein–Ponndorf–Verley Reaction
    Inorg. Chem. 2021

    M. Kobylarski, L. Monsigny, P. Thuéry, J.-C. Berthet*, T. Cantat*

  • The Role of (tBuPOCOP)Ir(I) and iridium(III) Pincer Complexes in the Catalytic Hydrogenolysis of Silyl Triflates into Hydrosilanes
    Organometallics 2021

    G. Durin, J.-C. Berthet, E. Nicolas, P. Thuéry, T. Cantat*

  • A copper(I)-catalyzed sulfonylative Hiyama cross-coupling
    Chem. Eur. J. 2021

    A. Adenot, L. Anthore-Dalion, E. Nicolas, J.-C. Berthet, P. Thuéry, T. Cantat*

  • Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases
    ACS Catal. 2021

    G. Durin, J.-C. Berthet, E. Nicolas, T. Cantat*

  • Photocatalytic deoxygenation of N–O bonds with rhenium complexes: from the reduction of nitrous oxide to pyridine N-oxides
    Chem. Sci. 2021

    M. Kjellberg, A. Ohleier, P. Thuéry, E. Nicolas, L. Anthore-Dalion*, T. Cantat*

  • Copper–Ligand Cooperativity in H2 Activation Enables the Synthesis of Copper Hydride Complexes
    Organometallics 2021

    A. Aloisi, É. Crochet, E. Nicolas, J.-C. Berthet, C. Lescot, P. Thuéry, T. Cantat*

  • Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex
    Organometallics 2021

    N. Lentz, A. Aloisi, P. Thuéry, E. Nicolas, T. Cantat

  • Direct Carbon Isotope Exchange of Pharmaceuticals via Reversible Decyanation
    J. Am. Chem. Soc. 2021

    M. Feng, J. De Oliveira, A. Sallustrau, G. Destro, P. Thuéry, S. Roy, T. Cantat, C. S. Elmore, J. Blankenstein, F. Taran, and D. Audisio*

  • Coupling Electrocatalytic CO2 Reduction with Thermocatalysis Enables the Formation of a Lactone Monomer
    ChemSusChem 2021

    L. Ponsard, E. Nicolas, N. H. Tran, S. Lamaison, D. Wakerley, T. Cantat*, M. Fontecave

  • Catalytic challenges and strategies for the carbonylation of σ-bonds
    Green Chem. 2021

    T. Nasr Allah, L. Ponsard, E. Nicolas, T. Cantat*

  • Catalytic Disproportionation of Formic Acid to Methanol using Recyclable Silylformates
    Angew. Chem. Int. Ed. 2020

    C. Chauvier, A. Imberdis, P. Thuéry, T. Cantat*

  • Transition‐Metal‐Free Carbon Isotope Exchange of Phenyl Acetic Acids
    Angew. Chem. Int. Ed. 2020

    G. Destro, K. Horkka, O. Loreau, D.‐A. Buisson, L. Kingston, A. Del Vecchio, M. Schou, C. S. Elmore, F. Taran, T. Cantat, D. Audisio*

  • Catalytic Metal-Free Deoxygenation of Nitrous Oxide with Disilanes
    ACS Catalysis 2019

    L. Anthore-Dalion*, E. Nicolas, T. Cantat*

  • Transition-Metal-Free Acceptorless Decarbonylation of Formic Acid Enabled by a Liquid Chemical-Looping Strategy
    Angew. Chem. Int. Ed. 2019

    A. Imberdis, G. Lefèvre, T. Cantat*

  • SO2 conversion to sulfones: development and mechanistic insights of a sulfonylative Hiyama cross-coupling
    Chem. Commun. 2019

    A. Adenot, J. Char, N. von Wolff, G. Lefèvre, L. Anthore-Dalion, T. Cantat*

  • Breaking C–O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes
    ACS Catal. 2019

    L. Monsigny, P. Thuéry, J.-C. Berthet, T Cantat*

  • Carbonylation of C−N Bonds in Tertiary Amines Catalyzed by Low‐Valent Iron Catalysts
    Angew. Chem. Int. Ed. 2019

    T. N. Allah, S. Savourey, J.-C. Berthet, E. Nicolas, T Cantat*

  • Activation of SO2 by N/Si+ and N/B Frustrated Lewis Pairs: Experimental and Theoretical Comparison with CO2 Activation
    Chem. Eur. J. 2019

    A. Adenot, N. von Wolff, G. Lefèvre, J.-C. Berthet, P. Thuéry, T. Cantat*

  • Dynamic Carbon Isotope Exchange of Pharmaceuticals with Labeled CO2
    J. Am. Chem. Soc. 2019

    G. Destro, O. Loreau, E. Marcon, F. Taran, T.Cantat*, D. Audisio*

  • Depolymerization of Waste Plastics to Monomers and Chemicals Using a Hydrosilylation Strategy Facilitated by Brookhart’s Iridium(III) Catalyst
    ACS Sustainable Chem. Eng. 2018

    L. Monsigny, J.-C. Berthet, T. Cantat

  • Efficient reductive depolymerization of hardwood and softwood lignins with Brookhart's iridium(III) catalyst and hydrosilanes
    Green Chem. 2018

    L. Monsigny, E. Feghali, J.-C. Berthet, T. Cantat

  • Metal-Free and Alkali-Metal-Catalyzed Synthesis of Isoureas from Alcohols and Carbodiimides
    Angew. Chem. Int. Ed. 2018

    A. Imberdis, G. Lefèvre, P. Thuery, T. Cantat

  • Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates
    Chem. Commun. 2017

    C. Chauvier, T. Godou, T. Cantat

  • Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates
    Synlett 2017

    T. Godou, C. Chauvier, P. Thuery, T. Cantat

  • Synthesis of Aromatic Sulfones from SO2 and Organosilanes, Under Metal-free Conditions
    Angew. Chem. Int. Ed. 2017

    N. von Wolff, J. Char, X. Frogneux, T. Cantat

  • A Viewpoint on Chemical Reductions of Carbon–Oxygen Bonds in Renewable Feedstocks Including CO2 and Biomass
    ACS Catal. 2017

    C. Chauvier, T. Cantat

  • Structural insights into the nature of Fe0 and FeI low-valent species obtained upon reduction of Iron salts by Aryl Grignard reagents
    Inorg. Chem. 2017

    M. Clémancey, T. Cantat, G. Blondin, J.-M. Latour*, P. Dorlet*, G. Lefèvre*

  • Reactivity and Structural Diversity in the Reaction of Guanidine 1,5,7-Triazabicyclo[4.4.0]dec-5-ene with CO2, CS2, and Other Heterocumulenes
    Eur. J. Org. Chem. 2017

    N. von Wolff, C. Villiers, P. Thuéry, G. Lefèvre, M. Ephritikhine, T. Cantat

  • Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes
    Angew. Chem. Int. Ed. 2016

    C. Chauvier, P. Thuéry, T. Cantat

  • Complexes of the tripodal phosphine ligands PhSi(XPPh2)3 (X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2
    Dalton Trans. 2016

    A. Aloisi, J.-C. Berthet, C. Genre, P. Thuéry, T. Cantat

  • Implications of CO2 Activation by Frustrated Lewis Pairs in the Catalytic Hydroboration of CO2: A View Using N/Si+ Frustrated Lewis Pairs
    ACS Catal. 2016

    N. von Wolff, G. Lefèvre, J.-C. Berthet, P. Thuéry, T. Cantat

  • Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO2
    Chem. Commun. 2016

    A. Tlili, A. Voituriez, A. Marinetti, P. Thuéry, T. Cantat

  • Metal-free disproportionation of formic acid mediated by organoboranes
    Chem. Sci. 2016

    C. Chauvier, P. Thuéry, T. Cantat

  • Synthesis, structure and electrochemical behavior of new RPONOP (R = tBu, iPr) pincer complexes of Fe2+, Co2+, Ni2+ and Zn2+ ions
    C. R. Chimie 2016

    C. Lescot, S. Savourey, P. Thuéry, G. Lefèvre, J.-C. Berthet, T. Cantat

  • CO2 Conversion into Esters by Fluoride-Mediated Carboxylation of Organosilanes and Halide Derivatives
    Chem. Eur. J. 2016

    X. Frogneux, N. von Wolff, P. Thuéry, G. Lefèvre, T. Cantat

  • Bridging Amines with CO2: Organocatalyzed Reduction of CO2 to Aminals
    ACS Catal. 2015

    X. Frogneux, E. Blondiaux, P. Thuéry, T. Cantat

  • Room Temperature Organocatalyzed Reductive Depolymerization of Waste Polyethers, Polyesters, and Polycarbonates
    ChemSusChem 2015

    E. Feghali, T. Cantat

  • Convergent reductive depolymerization of wood lignin to isolated phenol derivatives by metal-free catalytic hydrosilylation
    Energy Environ. Sci. 2015

    E. Feghali, G. Carrot, P. Thuéry, C. Genre, T. Cantat

  • Metal-free dehydrogenation of formic acid to H2 and CO2 using boron-based catalysts
    Chem. Sci. 2015

    C. Chauvier, A. Tlili, C. das Neves Gomes, P. Thuéry, T. Cantat

  • Reductive functionalization of CO2 with amines: an entry to formamide, formamidine and methylamine derivatives
    Green Chem. 2015

    A. Tlili, E. Blondiaux, X. Frogneux, T. Cantat

  • Catalytic methylation of aromatic amines with formic acid as the unique carbon and hydrogen source
    Chem. Commun. 2014

    S. Savourey, G. Lefèvre, J.-C. Berthet, T. Cantat

  • Carbon Dioxide Reduction to Methylamines under Metal-Free Conditions
    Angew. Chem. Int. Ed. 2014

    E. Blondiaux, J. Pouessel, T. Cantat

  • Efficient Disproportionation of Formic Acid to Methanol Using Molecular Ruthenium Catalysts
    Angew. Chem. Int. Ed. 2014

    S. Savourey, G. Lefèvre, J.-C. Berthet, P. Thuéry, C. Genre, T. Cantat

  • Efficient metal-free hydrositylation of tertiary, secondary and primary amides to amines
    Chem. Commun. 2014

    E. Blondiaux, T. Cantat

  • Metal-Free Reduction of CO2 with Hydroboranes: Two Efficient Pathways at Play for the Reduction of CO2 to Methanol
    Chem. Eur. J. 2014

    C. das Neves Gomes, E. Blondiaux, P. Thuéry, T. Cantat

  • Catalytic hydrosilylation of oxalic acid: chemoselective formation of functionalized C-2-products
    Catal. Sci. Technol. 2014

    E. Feghali, O. Jacquet, P. Thuéry, T. Cantat

  • Iron–catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines
    Catal. Sci. Technol. 2014

    X. Frogneux, T. Cantat

  • Creating Added Value with a Waste: Methylation of Amines with CO2 and H2
    Angew. Chem. Int. Ed. 2014

    A. Tlili, X. Frogneux, E. Blondiaux, T. Cantat

  • Unprecedented organocatalytic reduction of lignin model compounds to phenols and primary alcohols using hydrosilanes
    Chem. Commun. 2013

    E. Feghali, T.Cantat

  • Nitrite complexes of the rare earth elements
    Dalton Trans. 2013

    J. Pouessel, P. Thuéry, J.-C. Berthet, T. Cantat

  • Pushing Back the Limits of Hydrosilylation: Unprecedented Catalytic Reduction of Organic Ureas to Formamidines
    ChemCatChem 2013

    J. Pouessel, O. Jacquet, T. Cantat

  • Revisiting the Chemistry of the Actinocenes [(η8-C8H8)2An] (An = U, Th) with Neutral Lewis Bases. Access to the Bent Sandwich Complexes [(η8-C8H8)2An(L)] with Thorium (L = py, 4,4′-bipy, tBuNC, R4phen)
    J. Am. Chem. Soc. 2013

    J.-C. Berthet, P. Thuéry, N. Garin, J.-P. Dognon, T. Cantat, M. Ephritikhine

  • CO2 as a C1-building block for the catalytic methylation of amines
    Chem. Sci. 2013

    O. Jacquet, X. Frogneux, C. Das Neves Gomes, T. Cantat

  • Nitrite complexes of uranium and thorium
    Chem. Commun. 2013

    F. Dulong, J. Pouessel, P. Thuéry, J.-C. Berthet, M. Ephritikhine, T. Cantat

  • Synthesis of N-Aryloxy-β-diketiminate Ligands and Coordination to Zirconium, Ytterbium, Thorium, and Uranium
    Organometallics 2013

    F. Dulong, P. Thuéry, M. Ephritikhine, T. Cantat

  • Complete Catalytic Deoxygenation of CO2 into Formamidine Derivatives
    ChemCatChem 2013

    O. Jacquet, C. Das Neves Gomes, M. Ephritikhine, T. Cantat

  • Recycling of Carbon and Silicon Wastes: Room Temperature Formylation of N–H Bonds Using Carbon Dioxide and Polymethylhydrosiloxane
    J. Am. Chem. Soc. 2012

    O. Jacquet, C. Das Neves Gomes, M. Ephritikhine, T. Cantat

  • A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2
    Angew. Chem. Int. Ed. 2012

    C. Das Neves Gomes, O. Jacquet, C. Villiers, P. Thuéry, M. Ephritikhine, T. Cantat

  • A N-aryloxy-beta-diketiminate ligand in 4d, 4f and 5f-metals complexes
    Dalton Trans. 2012

    F. Dulong, O. Bathily, P. Thuery, M. Ephritikhine, T. Cantat,

  • Uranium(IV) Nucleophilic Carbene Complexes
    Organometallics 2011

    J. C. Tourneux, J. C. Berthet, T. Cantat, P. Thuéry, N. Mézailles, P. Le Floch, M. Ephritikhine

  • Exploring the Uranyl Organometallic Chemistry: From Single to Double Uranium−Carbon Bonds
    J. Am. Chem. Soc. 2011

    J. C. Tourneux, J. C. Berthet, T. Cantat, P. Thuéry, N. Mézailles, M.Ephritikhine