Publications
Metal-Free Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with "Inverse" Frustrated Lewis Pairs
Chem. Eur. J. 2023 G. Durin, J.-C. Berthet, P. Thuéry, E. Nicolas, T. Cantat*
Catalyst-free depolymerization of polycaprolactone to silylated monoesters and iodide derivatives using iodosilanes
Chem.Commun. 2023 X. Liu, M. Kobylarski, J.-C. Berthet*, T. Cantat*
Catalytic Carbonylation of Acrylic Acid to Succinic Anhydride
ChemCatChem 2023 M.-H. Pietraru, N. Lentz, L. Ponsard, E. Nicolas*, T. Cantat*
Activation of N−O σ Bonds with Transition Metals: A Versatile Platform for Organic Synthesis and C−N Bonds Formation
Eur. J. Org. Chem. 2023 U. Todorovic, R. M. Romero, L. Anthore-Dalion*
Evaluation of acetophenone as a novel alcohol-cycloalkane bifunctional liquid organic hydrogen carrier (LOHC)
Int. J. Hydrog. Energy 2023 F. D'Ambra, J. Levy, P. Hajiyev, T. Cantat, G. Gébel, V. Faucheux, E. Nicolas*
Catalytic Methoxylation of Aryl Halides Using 13C- and 14C-Labeled CO2
Chem. Commun. 2022 A. Ohleier, A. Sallustrau, B. Mouhsine, F. Caillé*, D. Audisio*, T.Cantat*
Zirconium-catalysed hydrosilylation of esters and depolymerisation of polyester plastic waste
Green Chem. 2022 M. Kobylarski, L. J. Donnelly*, J.-C. Berthet, T. Cantat*
Alkyl Formates as Transfer Hydroalkylation Reagents and Their Use in the Conversion of Imines to Alkylamines
Angew. Chem. Int. Ed. 2022 E. Crochet, L. Anthore-Dalion, T. Cantat*
Selective Reduction of Secondary Amides to Imines Catalysed by Schwartz's Reagent
Angew. Chem. Int. Ed. 2022 L. J. Donnelly*, J.-C. Berthet, T. Cantat*
Metal-free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes
Angew. Chem. Int. Ed. 2022 G. Durin, A. Fontaine, J.-C. Berthet, E. Nicolas, P. Thuéry, T. Cantat*
Reductive depolymerization of polyesters and polycarbonates with hydroboranes by using a lanthanum(iii) tris(amide) catalyst
Chem. Commun. 2022 M. Kobylarski, J.-C. Berthet*, T. Cantat*
Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones
Chem. Commun. 2022 R. M. Romero, N. Thyagarajan, N. Hellou, C. Chauvier, T. Godou, L. Anthore-Dalion, T. Cantat*
Additive-free selective methylation of secondary amines with formic acid over a Pd/In2O3 catalyst
Catal. Sci. Technol. 2022 C. Genre*, I. Benaissa, T. Godou, M. Pinault, T. Cantat*
Uranyl(VI) Triflate as Catalyst for the Meerwein–Ponndorf–Verley Reaction
Inorg. Chem. 2021 M. Kobylarski, L. Monsigny, P. Thuéry, J.-C. Berthet*, T. Cantat*
The Role of (tBuPOCOP)Ir(I) and iridium(III) Pincer Complexes in the Catalytic Hydrogenolysis of Silyl Triflates into Hydrosilanes
Organometallics 2021 G. Durin, J.-C. Berthet, E. Nicolas, P. Thuéry, T. Cantat*
A copper(I)-catalyzed sulfonylative Hiyama cross-coupling
Chem. Eur. J. 2021 A. Adenot, L. Anthore-Dalion, E. Nicolas, J.-C. Berthet, P. Thuéry, T. Cantat*
Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases
ACS Catal. 2021 G. Durin, J.-C. Berthet, E. Nicolas, T. Cantat*
Photocatalytic deoxygenation of N–O bonds with rhenium complexes: from the reduction of nitrous oxide to pyridine N-oxides
Chem. Sci. 2021 M. Kjellberg, A. Ohleier, P. Thuéry, E. Nicolas, L. Anthore-Dalion*, T. Cantat*
Copper–Ligand Cooperativity in H2 Activation Enables the Synthesis of Copper Hydride Complexes
Organometallics 2021 A. Aloisi, É. Crochet, E. Nicolas, J.-C. Berthet, C. Lescot, P. Thuéry, T. Cantat*
Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex
Organometallics 2021 N. Lentz, A. Aloisi, P. Thuéry, E. Nicolas, T. Cantat
Direct Carbon Isotope Exchange of Pharmaceuticals via Reversible Decyanation
J. Am. Chem. Soc. 2021 M. Feng, J. De Oliveira, A. Sallustrau, G. Destro, P. Thuéry, S. Roy, T. Cantat, C. S. Elmore, J. Blankenstein, F. Taran, and D. Audisio*
Coupling Electrocatalytic CO2 Reduction with Thermocatalysis Enables the Formation of a Lactone Monomer
ChemSusChem 2021 L. Ponsard, E. Nicolas, N. H. Tran, S. Lamaison, D. Wakerley, T. Cantat*, M. Fontecave
Catalytic challenges and strategies for the carbonylation of σ-bonds
Green Chem. 2021 T. Nasr Allah, L. Ponsard, E. Nicolas, T. Cantat*
Catalytic Disproportionation of Formic Acid to Methanol using Recyclable Silylformates
Angew. Chem. Int. Ed. 2020 C. Chauvier, A. Imberdis, P. Thuéry, T. Cantat*
Transition‐Metal‐Free Carbon Isotope Exchange of Phenyl Acetic Acids
Angew. Chem. Int. Ed. 2020 G. Destro, K. Horkka, O. Loreau, D.‐A. Buisson, L. Kingston, A. Del Vecchio, M. Schou, C. S. Elmore, F. Taran, T. Cantat, D. Audisio*
Catalytic Metal-Free Deoxygenation of Nitrous Oxide with Disilanes
ACS Catalysis 2019 L. Anthore-Dalion*, E. Nicolas, T. Cantat*
Transition-Metal-Free Acceptorless Decarbonylation of Formic Acid Enabled by a Liquid Chemical-Looping Strategy
Angew. Chem. Int. Ed. 2019 A. Imberdis, G. Lefèvre, T. Cantat*
SO2 conversion to sulfones: development and mechanistic insights of a sulfonylative Hiyama cross-coupling
Chem. Commun. 2019 A. Adenot, J. Char, N. von Wolff, G. Lefèvre, L. Anthore-Dalion, T. Cantat*
Breaking C–O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes
ACS Catal. 2019 L. Monsigny, P. Thuéry, J.-C. Berthet, T Cantat*
Carbonylation of C−N Bonds in Tertiary Amines Catalyzed by Low‐Valent Iron Catalysts
Angew. Chem. Int. Ed. 2019 T. N. Allah, S. Savourey, J.-C. Berthet, E. Nicolas, T Cantat*
Activation of SO2 by N/Si+ and N/B Frustrated Lewis Pairs: Experimental and Theoretical Comparison with CO2 Activation
Chem. Eur. J. 2019 A. Adenot, N. von Wolff, G. Lefèvre, J.-C. Berthet, P. Thuéry, T. Cantat*
Dynamic Carbon Isotope Exchange of Pharmaceuticals with Labeled CO2
J. Am. Chem. Soc. 2019 G. Destro, O. Loreau, E. Marcon, F. Taran, T.Cantat*, D. Audisio*
Depolymerization of Waste Plastics to Monomers and Chemicals Using a Hydrosilylation Strategy Facilitated by Brookhart’s Iridium(III) Catalyst
ACS Sustainable Chem. Eng. 2018 L. Monsigny, J.-C. Berthet, T. Cantat
Efficient reductive depolymerization of hardwood and softwood lignins with Brookhart's iridium(III) catalyst and hydrosilanes
Green Chem. 2018 L. Monsigny, E. Feghali, J.-C. Berthet, T. Cantat
Metal-Free and Alkali-Metal-Catalyzed Synthesis of Isoureas from Alcohols and Carbodiimides
Angew. Chem. Int. Ed. 2018 A. Imberdis, G. Lefèvre, P. Thuery, T. Cantat
Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates
Chem. Commun. 2017 C. Chauvier, T. Godou, T. Cantat
Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates
Synlett 2017 T. Godou, C. Chauvier, P. Thuery, T. Cantat
Synthesis of Aromatic Sulfones from SO2 and Organosilanes, Under Metal-free Conditions
Angew. Chem. Int. Ed. 2017 N. von Wolff†, J. Char†, X. Frogneux, T. Cantat
A Viewpoint on Chemical Reductions of Carbon–Oxygen Bonds in Renewable Feedstocks Including CO2 and Biomass
ACS Catal. 2017 C. Chauvier, T. Cantat
Structural insights into the nature of Fe0 and FeI low-valent species obtained upon reduction of Iron salts by Aryl Grignard reagents
Inorg. Chem. 2017 M. Clémancey, T. Cantat, G. Blondin, J.-M. Latour*, P. Dorlet*, G. Lefèvre*
Reactivity and Structural Diversity in the Reaction of Guanidine 1,5,7-Triazabicyclo[4.4.0]dec-5-ene with CO2, CS2, and Other Heterocumulenes
Eur. J. Org. Chem. 2017 N. von Wolff, C. Villiers, P. Thuéry, G. Lefèvre, M. Ephritikhine, T. Cantat
Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes
Angew. Chem. Int. Ed. 2016 C. Chauvier, P. Thuéry, T. Cantat
Complexes of the tripodal phosphine ligands PhSi(XPPh2)3 (X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2
Dalton Trans. 2016 A. Aloisi, J.-C. Berthet, C. Genre, P. Thuéry, T. Cantat
Implications of CO2 Activation by Frustrated Lewis Pairs in the Catalytic Hydroboration of CO2: A View Using N/Si+ Frustrated Lewis Pairs
ACS Catal. 2016 N. von Wolff, G. Lefèvre, J.-C. Berthet, P. Thuéry, T. Cantat
Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO2
Chem. Commun. 2016 A. Tlili, A. Voituriez, A. Marinetti, P. Thuéry, T. Cantat
Metal-free disproportionation of formic acid mediated by organoboranes
Chem. Sci. 2016 C. Chauvier, P. Thuéry, T. Cantat
Synthesis, structure and electrochemical behavior of new RPONOP (R = tBu, iPr) pincer complexes of Fe2+, Co2+, Ni2+ and Zn2+ ions
C. R. Chimie 2016 C. Lescot, S. Savourey, P. Thuéry, G. Lefèvre, J.-C. Berthet, T. Cantat
CO2 Conversion into Esters by Fluoride-Mediated Carboxylation of Organosilanes and Halide Derivatives
Chem. Eur. J. 2016 X. Frogneux†, N. von Wolff†, P. Thuéry, G. Lefèvre, T. Cantat
Bridging Amines with CO2: Organocatalyzed Reduction of CO2 to Aminals
ACS Catal. 2015 X. Frogneux, E. Blondiaux, P. Thuéry, T. Cantat
Room Temperature Organocatalyzed Reductive Depolymerization of Waste Polyethers, Polyesters, and Polycarbonates
ChemSusChem 2015 E. Feghali, T. Cantat
Convergent reductive depolymerization of wood lignin to isolated phenol derivatives by metal-free catalytic hydrosilylation
Energy Environ. Sci. 2015 E. Feghali, G. Carrot, P. Thuéry, C. Genre, T. Cantat
Metal-free dehydrogenation of formic acid to H2 and CO2 using boron-based catalysts
Chem. Sci. 2015 C. Chauvier, A. Tlili, C. das Neves Gomes, P. Thuéry, T. Cantat
Reductive functionalization of CO2 with amines: an entry to formamide, formamidine and methylamine derivatives
Green Chem. 2015 A. Tlili, E. Blondiaux, X. Frogneux, T. Cantat
Catalytic methylation of aromatic amines with formic acid as the unique carbon and hydrogen source
Chem. Commun. 2014 S. Savourey, G. Lefèvre, J.-C. Berthet, T. Cantat
Carbon Dioxide Reduction to Methylamines under Metal-Free Conditions
Angew. Chem. Int. Ed. 2014 E. Blondiaux, J. Pouessel, T. Cantat
Efficient Disproportionation of Formic Acid to Methanol Using Molecular Ruthenium Catalysts
Angew. Chem. Int. Ed. 2014 S. Savourey, G. Lefèvre, J.-C. Berthet, P. Thuéry, C. Genre, T. Cantat
Efficient metal-free hydrositylation of tertiary, secondary and primary amides to amines
Chem. Commun. 2014 E. Blondiaux, T. Cantat
Metal-Free Reduction of CO2 with Hydroboranes: Two Efficient Pathways at Play for the Reduction of CO2 to Methanol
Chem. Eur. J. 2014 C. das Neves Gomes, E. Blondiaux, P. Thuéry, T. Cantat
Catalytic hydrosilylation of oxalic acid: chemoselective formation of functionalized C-2-products
Catal. Sci. Technol. 2014 E. Feghali, O. Jacquet, P. Thuéry, T. Cantat
Iron–catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines
Catal. Sci. Technol. 2014 X. Frogneux, T. Cantat
Creating Added Value with a Waste: Methylation of Amines with CO2 and H2
Angew. Chem. Int. Ed. 2014 A. Tlili, X. Frogneux, E. Blondiaux, T. Cantat
Unprecedented organocatalytic reduction of lignin model compounds to phenols and primary alcohols using hydrosilanes
Chem. Commun. 2013 E. Feghali, T.Cantat
Nitrite complexes of the rare earth elements
Dalton Trans. 2013 J. Pouessel, P. Thuéry, J.-C. Berthet, T. Cantat
Pushing Back the Limits of Hydrosilylation: Unprecedented Catalytic Reduction of Organic Ureas to Formamidines
ChemCatChem 2013 J. Pouessel, O. Jacquet, T. Cantat
Revisiting the Chemistry of the Actinocenes [(η8-C8H8)2An] (An = U, Th) with Neutral Lewis Bases. Access to the Bent Sandwich Complexes [(η8-C8H8)2An(L)] with Thorium (L = py, 4,4′-bipy, tBuNC, R4phen)
J. Am. Chem. Soc. 2013 J.-C. Berthet, P. Thuéry, N. Garin, J.-P. Dognon, T. Cantat, M. Ephritikhine
CO2 as a C1-building block for the catalytic methylation of amines
Chem. Sci. 2013 O. Jacquet, X. Frogneux, C. Das Neves Gomes, T. Cantat
Nitrite complexes of uranium and thorium
Chem. Commun. 2013 F. Dulong, J. Pouessel, P. Thuéry, J.-C. Berthet, M. Ephritikhine, T. Cantat
Synthesis of N-Aryloxy-β-diketiminate Ligands and Coordination to Zirconium, Ytterbium, Thorium, and Uranium
Organometallics 2013 F. Dulong, P. Thuéry, M. Ephritikhine, T. Cantat
Complete Catalytic Deoxygenation of CO2 into Formamidine Derivatives
ChemCatChem 2013 O. Jacquet, C. Das Neves Gomes, M. Ephritikhine, T. Cantat
Recycling of Carbon and Silicon Wastes: Room Temperature Formylation of N–H Bonds Using Carbon Dioxide and Polymethylhydrosiloxane
J. Am. Chem. Soc. 2012 O. Jacquet, C. Das Neves Gomes, M. Ephritikhine, T. Cantat
A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2
Angew. Chem. Int. Ed. 2012 C. Das Neves Gomes, O. Jacquet, C. Villiers, P. Thuéry, M. Ephritikhine, T. Cantat
A N-aryloxy-beta-diketiminate ligand in 4d, 4f and 5f-metals complexes
Dalton Trans. 2012 F. Dulong, O. Bathily, P. Thuery, M. Ephritikhine, T. Cantat,
Uranium(IV) Nucleophilic Carbene Complexes
Organometallics 2011 J. C. Tourneux, J. C. Berthet, T. Cantat, P. Thuéry, N. Mézailles, P. Le Floch, M. Ephritikhine
Exploring the Uranyl Organometallic Chemistry: From Single to Double Uranium−Carbon Bonds
J. Am. Chem. Soc. 2011 J. C. Tourneux, J. C. Berthet, T. Cantat, P. Thuéry, N. Mézailles, M.Ephritikhine