Pickering emulsions

Microfluidic emulsion generator

Emulsions of two immiscible fluids stabilized with solids particles, called Pickering emulsion, have been studied since the early twentieth century and the pioneering works of Ramsden[1] and Pickering[2] The irreversible adsorption of particles at the interface of the two phases gives original properties of these emulsions. Such emulsions are of primary interest in the food, cosmetics industry and oil recovery. Although it is now clear that the stabilization mechanism comes from the partial wettability of the nanoparticles by the two emulsion phases, the interface structures for such a stability mechanism is not well understood. There is a need of making a Pickering emulsion model system where the nanoparticles are well controlled as well as the emulsion size. The LIONS laboratory has developed a microfluidics platform (Fig.6) which allows preparing monodisperse tunable Pickering emulsion starting from monodisperse silica nanoparticles (NPs) of 7nm radius.

 

[1] Ramsden, W.,  Proceedings of the Royal Society of London, 72 (477-486), 156-164 (1903).

[2] Pickering, S. U. J.,  Chem. Soc, 91, 2001-2021 (1907).

 

Surface coverage of the microfluidic prepared emulsions as a function of ageing time for three NPs initial concentrations

A surface coverage as low as 23% is enough to stabilize the emulsions and we evidence a new regime of Pickering emulsion stability where the surface coverage of constant size emulsion droplets increases in time, in coexistence with a large amount of dispersed phase. Our results demonstrate that the previously observed limited coalescence regime where the average size of the final droplets is controlled by surface coverage (Fig.7) must be put in a broader perspective[1] [2].

 

[1] Fouilloux, S. PhD thesis (2011).

[2] Patent, B01D17/05.

 

Maj : 29/11/2013 (2245)

 

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