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A methodology for Raman structural quantification imaging and its application to iron indoor atmospheric corrosion product
a SIS2M/LAPA and LADIR CNRS collaboration
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A methodology for Raman structural quantification imaging and its application to iron indoor atmospheric corrosion product

Raman structural imaging of the sample Am XXX S.(a) Optical microphotograph with the location of the scanned area (C5). Semi-quantitative results obtained from spectral decomposition by LADIR-CAT program for (b) goethite (c) hydrated Fe(III) oxi-(hydroxi)de
(d) lepidocrocite (e) akaganeite

Raman structural imaging can extract original information in order to answer new questions raised in the recent studies on
iron and low alloy steel corrosion. Up to now, this technique has allowed the extraction of the qualitative distribution of the
compounds constituting the corrosion product layers.Wepropose here amethodology to extract quantitative parameters from Raman hyperspectral maps, executed by a home-developed software: LADIR-CAT. Specifically developed for iron corrosion quantitative component imaging, the approach and program operation are described. The LADIR-CAT is applied on ancient corroded iron samples originating from the Amiens cathedral (France) to establish the description and the composition of the corrosion systemthrough quantitative compound imaging.

 

Monnier, J., Bellot-Gurlet, L., Baron, D., Neff, D., Guillot, I., Dillmann, P., 2011. A methodology for Raman structural quantification imaging and its application to iron indoor atmospheric corrosion products, Journal of Raman Spectroscopy, 23-42.

 
#1757 - Last update : 03/13 2014

 

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