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Photo- and Mechano-Responsive Fluorescent Molecular Nanosystems
Rémi METIVIER
Laboratoire PPSM, ENS Cachan, CNRS, Université Paris-Saclay
Fri, Jan. 18th 2019, 11:00-12:00
LIDYL Bât.522, Grande salle 137-138, CEA-Saclay

The field of advanced fluorescent nanomaterials, with photo-induced or mechano-induced switching capabilities, is extremely active and has been attracting ever-growing interest in recent years in many research fields for their potential applications in biological sensors, high-resolution imaging, and innovative materials science.[1] We report here on the design, fabrication, spectroscopy and microscopy of two different kinds of systems, from the ensemble level down to the single nanoparticle level, with the aim to quantify the photo- or mechano-switching efficiency.

First, photoswitchable emissive nanoparticles, based on dyad molecules combining photochromic and fluorescent moieties, were prepared and characterized. In depth photophysical study revealed that the emission signal could be successfully and reversibly switched by light by means of multiple energy transfer pathways, leading to an unprecedented giant amplification of fluorescence photoswitching (Fig. 1A-B).[2]

Second, difluoroboron-b-diketone organic materials were synthesized, showing fluorescence and morphology modifications upon mechanical and thermal treatments.[3,4] Molecular nanocrystals were obtained by the reprecipitation method, then investigated by fluorescence microscopy combined with atomic force microscopy, highlighting the specific mechanofluorochromic behaviour of this material at the nanoscale (Fig. 1C).

Metivier_IUPAC2018_Figure

Figure 1. (A, B) Giant amplification of fluorescence photoswitching based on photochromic-fluorescent nanoparticles, and (C) mechanofluorochromic properties of difluoroboron-b-diketone nanocrystals.

References

1. B. L. Feringa, W. R. Brown, “Molecular Switches”, 2nd ed., Weinheim, Wiley-VCH (2011).

2. J. Su, T. Fukaminato, J. P. Placial, T. Onodera, R. Suzuki, H. Oikawa, A. Brosseau, F. Brisset, R. Pansu, K. Nakatani, R. Métivier, Angew. Chem. Int. Ed. 2016, 55, 3662-3666. (inside cover); T. Fukaminato, S. Ishida, R. Métivier, NPG Asia Mater. 2018, DOI: 10.1038/s41427-018-0075-9.

3. Z. Chi, X. Zhang, B. Xu, X. Zhou, C. Ma, Y. Zhang, S. Liu, J. Xu, Chem. Soc. Rev., 2012, 41, 3878.

4. M. Louis, A. Brosseau, R. Guillot, F. Ito, C. Allain, R. Métivier, J. Phys. Chem. C 2017, 121, 15897; L. Wilbraham, M. Louis, D. Alberga, A. Brosseau, R. Guillot, F. Ito, F. Labat, R. Métivier, C. Allain, I. Ciofini, Adv. Mater. 2018, 30, 1800817.

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