Publications

Refereed publications from CEA


[76-CEA]
Gianluca Destro, Olivier Loreau, Elodie Marcon, Frédéric Taran, Thibault Cantat*, and Davide Audisio*, J. Am. Chem. Soc. 2019, 141, 2, 780-784.
Dynamic Carbon Isotope Exchange of Pharmaceuticals with Labeled CO2
[75-CEA]
L. Monsigny, J.-C. Berthet and T. Cantat, ACS Sustainable Chem. Eng. 2018, 6, 8, 10481-10488.
Depolymerization of Waste Plastics to Monomers and Chemicals Using a Hydrosilylation Strategy Facilitated by Brookhart’s Iridium(III) Catalyst
[74-CEA]
L. Monsigny, E. Feghali, J.-C. Berthet and T. Cantat, Green Chem., 2018, 20, 1981-1986.
Efficient reductive depolymerization of hardwood and softwood lignins with Brookhart's iridium(III) catalyst and hydrosilanes
[73-CEA]
A. Imberdis, G. Lefèvre, P. Thuery, T. Cantat, Angew. Chem. Int. Ed. 2018, 57, 3084-3088.
Metal-Free and Alkali-Metal-Catalyzed Synthesis of Isoureas from Alcohols and Carbodiimides
[72-CEA]
C. Chauvier, T. Godou, T. Cantat, Chem. Commun., 2017,53, 11697-11700.
Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates
[71-CEA]
T. Godou, C. Chauvier, P. Thuery, T. Cantat,  Synlett 2017, 28, 2473-2477.
Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates
[70-CEA]
N. von Wolff#, C. Char#, X. Frogneux, T. Cantat, Angew. Chem. Int. Ed. 2017, 56, 5616-5619.
Synthesis of Aromatic Sulfones from SO2 and Organosilanes, Under Metal-free Conditions
[69-CEA]
C. Chauvier, T. Cantat, ACS Catal. 2017, 7, 2107-2115.
A Viewpoint on Chemical Reductions of Carbon–Oxygen Bonds in Renewable Feedstocks Including CO2 and Biomass
[68-CEA]
M. Clémancey, T. Cantat, G. Blondin, J.-M. Latour, P. Dorlet, G. Lefèvre, Inorg. Chem. 2017, 56, 3834-3848.
Structural insights into the nature of Fe0 and FeI low-valent species obtained upon reduction of Iron salts by Aryl Grignard reagents
[67-CEA]
N. von Wolff, C. Villiers, P. Thuery, G. Lefevre, M. Ephritikhine, T. Cantat, Eur. J. Org. Chem. 2017, 676-686.
Reactivity and Structural Diversity in the Reaction of Guanidine 1,5,7-Triazabicyclo[4.4.0]dec-5-ene with CO2, CS2, and Other Heterocumulenes
[66-CEA]
N. von Wolff, G. Lefevre, J. C. Berthet, P. Thuery, T. Cantat, ACS Catal. 2016, 6, 4526-4535.
Implications of CO2 Activation by Frustrated Lewis Pairs in the Catalytic Hydroboration of CO2: A View Using N/Si+ Frustrated Lewis Pairs
[65-CEA]
A. Tlili, A. Voituriez, A. Marinetti, P. Thuery, T. Cantat, Chem. Commun. 2016, 52, 7553-7555.
Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO2
[64-CEA]
C. Lescot, S. Savourey, P. Thuery, G. Lefevre, J. C. Berthet, T. Cantat, C. R. Chimie. 2016, 19, 57-70.
Synthesis, structure and electrochemical behavior of new (PONOP)-P-R (R = Bu-t, Pr-i) pincer complexes of Fe2+,Co2+, Ni2+, and Zn2+ ions
[63-CEA]
X. Frogneux#, N. von Wolff#, P. Thuery, G. Lefevre, T. Cantat, Chem.-Eur. J. 2016, 22, 2930-2934.
CO 2 Conversion into Esters by Fluoride-Mediated Carboxylation of Organosilanes and Halide Derivatives
[62-CEA]
C. Chauvier, P. Thuery, T. Cantat, Chem. Sci. 2016, 7, 5680-5685.
Metal-free disproportionation of formic acid mediated by organoboranes
[61-CEA]
C. Chauvier, P. Thuery, T. Cantat, Angew. Chem. Int. Ed. 2016, 55, 14096-14100.
Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes
[60-CEA]
A. Aloisi, J. C. Berthet, C. Genre, P. Thuery, T. Cantat, Dalton Trans. 2016, 45, 14774-14788.
Complexes of the tripodal phosphine ligands PhSi(XPPH2) 3 (X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2
XXX:Invited contribution to the special issue XXX
[59-CEA]
A. Tlili, E. Blondiaux, X. Frogneux, T. Cantat, Green Chem. 2015, 17, 157-168.
Reductive functionalization of CO2 with amines: an entry to formamide, formamidine and methylamine derivatives
Highly CIted PaperHighly cited paper in Web of ScienceTM
[58-CEA]
X. Frogneux, E. Blondiaux, P. Thuery, T. Cantat, ACS Catal. 2015, 5, 3983-3987.
Bridging Amines with CO2: Organocatalyzed Reduction of CO 2 to Aminals
[57-CEA]
E. Feghali, G. Carrot, P. Thuery, C. Genre, T. Cantat, Energy. Environ. Sci. 2015, 8, 2734-2743.
Convergent reductive depolymerization of wood lignin to isolated phenol derivatives by metal-free catalytic hydrosilylation
[56-CEA]
E. Feghali, T. Cantat, ChemSusChem 2015, 8, 980-984.
Room Temperature Organocatalyzed Reductive Depolymerization of Waste Polyethers, Polyesters, and Polycarbonates
[55-CEA]
C. Chauvier, A. Tlili, C. D. Gomes, P. Thuery, T. Cantat, Chem. Sci. 2015, 6, 2938-2942.
Metal-free dehydrogenation of formic acid to H2 and CO 2 using boron-based catalysts
[54-CEA]
A. Tlili, X. Frogneux, E. Blondiaux, T. Cantat, Angew. Chem. Int. Ed. 2014, 53, 2543-2545.
Creating Added Value with a Waste: Methylation of Amines with CO2 and H2
[53-CEA]
S. Savourey, G. Lefevre, J. C. Berthet, P. Thuery, C. Genre, T. Cantat, Angew. Chem. Int. Ed. 2014, 53, 10466-10470.
Efficient Disproportionation of Formic Acid to Methanol Using Molecular Ruthenium Catalysts
[52-CEA]
S. Savourey, G. Lefevre, J. C. Berthet, T. Cantat, Chem. Commun. 2014, 50, 14033-14036.
Catalytic methylation of aromatic amines with formic acid as the unique carbon and hydrogen source
[51-CEA]
J. Pouessel, P. Thuery, J. C. Berthet, T. Cantat, Dalton Trans. 2014, 43, 4415-4425.
Nitrite complexes of the rare earth elements
[50-CEA]
W. L. Huang, F. Dulong, S. I. Khan, T. Cantat, P. L. Diaconescu, J. Am. Chem. Soc. 2014, 136, 17410-17413.
Bimetallic Cleavage of Aromatic C-H Bonds by Rare-Earth-Metal Complexes
[49-CEA]
C. D. Gomes, E. Blondiaux, P. Thuery, T. Cantat, Chem.-Eur. J. 2014, 20, 7098-7106.
Metal-Free Reduction of CO2 with Hydroboranes: Two Efficient Pathways at Play for the Reduction of CO2 to Methanol
[48-CEA]
X. Frogneux, O. Jacquet, T. Cantat, Catal. Sci. Technol. 2014, 4, 1529-1533.
Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines
[47-CEA]
E. Feghali, O. Jacquet, P. Thuery, T. Cantat, Catal. Sci. Technol. 2014, 4, 2230-2234.
Catalytic hydrosilylation of oxalic acid: chemoselective formation of functionalized C2-products
[46-CEA]
E. Feghali, T. Cantat, Chem. Commun. 2014, 50, 862-865.
Unprecedented organocatalytic reduction of lignin model compounds to phenols and primary alcohols using hydrosilanes
[45-CEA]
E. Blondiaux, J. Pouessel, T. Cantat, Angew. Chem. Int. Ed. 2014, 53, 12186-12190.
Carbon Dioxide Reduction to Methylamines under Metal-Free Conditions
[44-CEA]
E. Blondiaux, T. Cantat, Chem. Commun. 2014, 50, 9349-9352.
Efficient metal-free hydrositylation of tertiary, secondary and primary amides to amines
[43-CEA]
J. Pouessel, O. Jacquet, T. Cantat, ChemCatChem 2013, 5, 3552-3556.
Pushing Back the Limits of Hydrosilylation: Unprecedented Catalytic Reduction of Organic Ureas to Formamidines
[42-CEA]
O. Jacquet, C. D. Gomes, M. Ephritikhine, T. Cantat, ChemCatChem 2013, 5, 117-120.
Complete Catalytic Deoxygenation of CO2 into Formamidine Derivatives
[41-CEA]
O. Jacquet, X. Frogneux, C. D. Gomes, T. Cantat, Chem. Sci. 2013, 4, 2127-2131.
CO 2 as a C1-building block for the catalytic methylation of amines
Highly CIted PaperHighly cited paper in Web of ScienceTM
[40-CEA]
W. L. Huang, F. Dulong, T. P. Wu, S. I. Khan, J. T. Miller, T. Cantat, P. L. Diaconescu, Nature Comm. 2013, 4, 1448.
A six-carbon 10 pi-electron aromatic system supported by group 3 metals
[39-CEA]
F. Dulong, P. Thuery, M. Ephritikhine, T. Cantat, Organometallics 2013, 32, 1328-1340.
Synthesis of N-Aryloxy-beta-diketiminate Ligands and Coordination to Zirconium, Ytterbium, Thorium, and Uranium
[38-CEA]
F. Dulong, J. Pouessel, P. Thuery, J. C. Berthet, M. Ephritikhine, T. Cantat, Chem. Commun. 2013, 49, 2412-2414.
Nitrite complexes of uranium and thorium
[37-CEA]
J. C. Berthet, P. Thuery, N. Garin, J. P. Dognon, T. Cantat, M. Ephritikhine, J. Am. Chem. Soc. 2013, 135, 10003-10006.
Revisiting the Chemistry of the Actinocenes [(eta(8)-C 8H8)(2)An] (An = U, Th) with Neutral Lewis Bases. Access to the Bent Sandwich Complexes [(eta(8)-C8H8)(2)An(L)] with Thorium (L = py, 4,4'-bipy, tBuNC, R(4)phen)
[36-CEA]
O. Jacquet, C. D. Gomes, M. Ephritikhine, T. Cantat, J. Am. Chem. Soc. 2012, 134, 2934-2937.
Recycling of Carbon and Silicon Wastes: Room Temperature Formylation of N-H Bonds Using Carbon Dioxide and Polymethylhydrosiloxane
[35-CEA]
C. D. Gomes, O. Jacquet, C. Villiers, P. Thuery, M. Ephritikhine, T. Cantat, Angew. Chem. Int. Ed. 2012, 51, 187-190.
A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2
Highly CIted PaperHighly cited paper in Web of ScienceTM
[34-CEA]
F. Dulong, O. Bathily, P. Thuery, M. Ephritikhine, T. Cantat, Dalton Trans. 2012, 41, 11980-11983.
A N-aryloxy-beta-diketiminate ligand in 4d, 4f and 5f-metals complexes
[33-CEA]
J. C. Tourneux, J. C. Berthet, T. Cantat, P. Thuery, N. Mézailles, P. Le Floch, M. Ephritikhine, Organometallics 2011, 30, 2957-2971.
Uranium(IV) Nucleophilic Carbene Complexes
[32-CEA]
J. C. Tourneux, J. C. Berthet, T. Cantat, P. Thuery, N. Mézailles, M. Ephritikhine, J. Am. Chem. Soc. 2011, 133, 6162-6165.
Exploring the Uranyl Organometallic Chemistry: From Single to Double Uranium-Carbon Bonds
[31-CEA]
E. M. Broderick, N. Guo, T. P. Wu, C. S. Vogel, C. L. Xu, J. Sutter, J. T. Miller, K. Meyer, T. Cantat, P. L. Diaconescu, Chem. Commun. 2011, 47, 9897-9899.
Redox control of a polymerization catalyst by changing the oxidation state of the metal center

Refereed publications from Los Alamos National Laboratory (postdoctoral studies)

[30-LANL]
F. L. Taw, A. E. Clark, A. H. Mueller, M. T. Janicke, T. Cantat, B. L. Scott, P. J. Hay, R. P. Hughes, J. L. Kiplinger, Organometallics 2012, 31, 1484-1499.
Titanium(IV) Trifluoromethyl Complexes: New Perspectives on Bonding from Organometallic Fluorocarbon Chemistry
[29-LANL]
M. J. Monreal, R. K. Thomson, T. Cantat, N. E. Travia, B. L. Scott, J. L. Kiplinger, Organometallics 2011, 30, 2031-2038.
UI 4(1,4-dioxane)2, [UCl4(1,4-dioxane)]2, and UI3(1,4-dioxane)1.5: Stable and Versatile Starting Materials for Low- and High-Valent Uranium Chemistry
[28-LANL]
R. K. Thomson, T. Cantat, B. L. Scott, D. E. Morris, E. R. Batista, J. L. Kiplinger, Nature Chem. 2010, 2, 723-729.
Uranium azide photolysis results in C-H bond activation and provides evidence for a terminal uranium nitride
[27-LANL]
E. J. Schelter, R. L. Wu, B. L. Scott, J. D. Thompson, T. Cantat, K. D. John, E. R. Batista, D. E. Morris, J. L. Kiplinger, Inorg. Chem. 2010, 49, 924-933.
Actinide Redox-Active Ligand Complexes: Reversible Intramolecular Electron-Transfer in U(dpp-BIAN)2/U(dpp-BIAN)2(THF)
[26-LANL]
T. Cantat, B. L. Scott, J. L. Kiplinger, Chem. Commun. 2010, 46, 919-921.
Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME) 2, ThCl4(1,4-dioxane)2 and ThCl4(THF)3.5 using commercially available and inexpensive starting materials
[25-LANL]
T. Cantat, B. L. Scott, D. E. Morris, J. L. Kiplinger, Inorg. Chem. 2009, 48, 2114-2127.
What a Difference a 5f Element Makes: Trivalent and Tetravalent Uranium Halide Complexes Supported by One and Two Bis[2-(diisopropylphosphino)-4-methylphenyl]amido (PNP) Ligands
[24-LANL]
T. Cantat, C. R. Graves, B. L. Scott, J. L. Kiplinger, Angew. Chem. Int. Ed. 2009, 48, 3681-3684.
Challenging the Metallocene Dominance in Actinide Chemistry with a Soft PNP Pincer Ligand: New Uranium Structures and Reactivity Patterns
[23-LANL]
C. R. Graves, E. J. Schelter, T. Cantat, B. L. Scott, J. L. Kiplinger, Organometallics 2008, 27, 5371-5378.
A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide
[22-LANL]
T. Cantat, C. R. Graves, K. C. Jantunen, C. J. Burns, B. L. Scott, E. J. Schelter, D. E. Morris, P. J. Hay, J. L. Kiplinger, J. Am. Chem. Soc. 2008, 130, 17537-17551.
Evidence for the Involvement of 5f Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes

Refereed publications from Ecole Polytechnique (doctoral studies)

[21-X]
H. Heuclin, T. Cantat, X. F. Le Goff, P. Le Floch, N. Mézailles, Eur. J. Inorg. Chem. 2011, 2540-2546.
Coordination Behavior of the S-C-S Monoanion and O-C-O and S-C-S Dianions toward Co-II
[20-X]
T. Cantat, T. Arliguie, A. Noel, P. Thuery, M. Ephritikhine, P. Le Floch, N. Mézailles, J. Am. Chem. Soc. 2009, 131, 963-972.
The U=C Double Bond: Synthesis and Study of Uranium Nucleophilic Carbene Complexes
[19-X]
M. Blug, H. Heuclin, T. Cantat, X. F. Le Goff, N. Mézailles, P. Le Floch, Organometallics 2009, 28, 1969-1972.
A Strained S similar to C similar to S Ir Pincer Complex: Intramolecular C-H Activation of an Aromatic Ring
[18-X]
T. Cantat, N. Mézailles, A. Auffrant, P. Le Floch, Dalton Trans. 2008, 1957-1972.
Bis-phosphorus stabilised carbene complexes
[17-X]
T. Cantat, F. Biaso, A. Momin, L. Ricard, M. Geoffroy, N. Mézailles, P. Le Floch, Chem. Commun. 2008, 874-876.
Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative
[16-X]
O. Piechaczyk, T. Cantat, N. Mézailles, P. Le Floch, J. Org. Chem. 2007, 72, 4228-4237.
A joint experimental and theoretical study of the palladium-catalyzed electrophilic allylation of aldehydes
[15-X]
A. Moores, T. Cantat, L. Ricard, N. Mézailles, P. Le Floch, New J. Chem. 2007, 31, 1493-1498.
Experimental and theoretical study of phosphinine sulfides
[14-X]
H. Lesnard, T. Cantat, P. Le Floch, I. Demachy, Y. Jean, Chem.-Eur. J. 2007, 13, 2953-2965.
2,2 '-biphosphinines and 2,2 '-bipyridines in homoleptic dianionic group 4 complexes and neutral 2,2 '-biphosphinine group 6 d(6) metal complexes: Octahedral versus trigonal-prismatic geometries
[13-X]
M. Doux, O. Piechaczyk, T. Cantat, N. Mézailles, P. Le Floch, C. R. Chim. 2007, 10, 573-582.
New anionic and dianionic polydentate systems featuring ancillary phosphinosulfides as ligands in coordination chemistry and catalysis
[12-X]
T. Cantat, X. Jacques, L. Ricard, X. F. Le Goff, N. Mézailles, P. Le Floch, Angew. Chem. Int. Ed. 2007, 46, 5947-5950.
From a stable dianion to a stable carbenoid
[11-X]
T. Cantat, L. Ricard, N. Mézailles, P. Le Floch, Organometallics 2006, 25, 6030-6038.
Synthesis, reactivity, and DFT studies of S-C-S zirconium(IV) complexes
[10-X]
T. Cantat, L. Ricard, P. Le Floch, N. Mézailles, Organometallics 2006, 25, 4965-4976.
Phosphorus-stabilized geminal dianions
[9-X]
T. Cantat, F. Jaroschik, L. Ricard, P. Le Floch, F. Nief, N. Mézailles, Organometallics 2006, 25, 1329-1332.
Thulium alkylidene complexes: Synthesis, X-ray structures, and reactivity
[8-X]
F. Biaso, T. Cantat, N. Mézailles, L. Ricard, P. Le Floch, M. Geoffroy, Angew. Chem. Int. Ed. 2006, 45, 7036-7039.
Formation and structure of a stable monoradical cation by reduction of a diphosphafulvenium salt
[7-X]
P. Adkine, T. Cantat, E. Deschamps, L. Ricard, N. Mézailles, P. Le Floch, M. Geoffroy, Phys. Chem. Chem. Phys. 2006, 8, 862-868.
EPR and DFT studies of the one-electron reduction product of phospholium cations
[6-X]
T. Cantat, F. Jaroschik, F. Nief, L. Ricard, N. Mézailles, P. Le Floch, Chem. Commun. 2005, 5178-5180.
New mono- and bis-carbene samarium complexes: synthesis, X-ray crystal structures and reactivity
[5-X]
T. Cantat, M. Demange, N. Mézailles, L. Ricard, Y. Jean, P. Le Floch, Organometallics 2005, 24, 4838-4841.
A bis(thiophosphinoyl)methylene ruthenium carbene complex: Synthesis, X-ray crystal structure, and DFT calculations of its thermally promoted reverse alpha-hydride migration process
[4-X]
T. Cantat, N. Mézailles, L. Ricard, Y. Jean, P. Le Floch, Angew. Chem. Int. Ed. 2004, 43, 6382-6385.
A bis(thiophosphinoyl)methanediide palladium complex: Coordinated dianion or nucleophilic carbene complex?
[3-X]
T. Cantat, N. Mézailles, N. Maigrot, L. Ricard, P. Le Floch, Chem. Commun. 2004, 1274-1275.
Titanocene and zirconocene complexes of a phosphorus analog of an Arduengo's carbene: Application in the synthesis of 1,3-diphosphafulvenes

Referred publications from Ecole Normale Superieure (predoctoral studies)

[2-ENS]
T. Cantat, N. Agenet, A. Jutand, R. Pleixats, M. Moreno-Manas, Eur. J. Org. Chem. 2005, 4277-4286.
The effect of chloride ions on the mechanism of the oxidative addition of cyclic allylic carbonates to Pd-0 complexes by formation of neutral [(eta(1)-allyl)PdClL2] complexes
[1-ENS]
T. Cantat, E. Genin, C. Giroud, G. Meyer, A. Jutand, J. Organomet. Chem. 2003, 687, 365-376.
Structural and kinetic effects of chloride ions in the palladium-catalyzed allylic substitutions

#: The authors contributed equally to the work.