lsalmon
Lionel SALMON
Chargé de Recherche - CNRS

DSM/DRECAM/SCM/LCCEf
0169085879
0169086640
salmondrecam.cea.fr

Sujets de recherche

Publications scientifiques


Sujets de recherche
Chimie de coordination de l'uranium

Synthèse et caractérisation de complexes moléculaires associant l’uranium et un métal de transition des séries d. Etude de leurs propriétés magnétiques.

Etude Structurale de nouveaux composés polynucléaires de l'uranium.

Synthèses et étude structurales de complexes de l'uranium avec des ligands macrocycliques (calixarene)

Publications scientifiques
Synthesis and crystal structure of uranium(IV) complexes with calix[n]arenes (n = 4, 6 and 8): mononuclear, polynuclear and 1D polymeric species.
L. Salmon, P. Thuéry and M. Ephritikhine, Dalton. Trans, 2006, submitted.

Uranium(V) and uranium(IV/V) mixed valence complexes with p-tert- butylhomocalix[n]arenes (n = 4, 6).
L. Salmon, P. Thuéry, S. Miyamoto, T. Yamato and M. Ephritikhine, Polyhedron, 2006, accepted.

Synthesis, crystal structure and reactivity of uranium(IV) complexes with p-tert- butylcalix[4]arene ligands.
L. Salmon, P. Thuéry, Z. Asfari and M. Ephritikhine, Dalton Trans., 2006, accepted

Uranium(IV) complexes of calix[n]arenes (n = 4, 6 and 8.
L. Salmon, P. Thuéry and M. Ephritikhine, Chem. Commun, 2006, 856.

Synthesis, structure and magnetic behavior of a series of trinuclear Schiff base complexes of 5f (UIV, ThIV) and 3d (CuII, ZnII) ions.
L. Salmon, P. Thuéry, E. Rivière and M. Ephritikhine, Inorg. Chem., 2006, 45, 83.

Polynuclear uranium compounds with μ-oxo-UIV core and compartmental Schiff base ligands.
L. Salmon, P. Thuéry and M. Ephritikhine, Polyhedron, 2006, 25, 1537.

A heterobimetallic zinc(II)/uranium(IV) complex with the Schiff base N, N'-bis(3-hydroxysalicylidene)-2-amino-benzylamine.
L. Salmon, P. Thuéry and M. Ephritikhine, Acta Crystallogr. Section E, 2005, E61, m2607.

Lanthanide(III) / actinide(III) differentiation in the cerium and uranium complexes [M(C5Me5)2(L)]0,+1 (L = 2,2'-bipyridine and 2,2':6',2''- terpyridine) from structural, magnetic and reactivity studies.
T. Mehdoui, J. C. Berthet, P. Thuéry, L. Salmon, E. Rivière and M. Ephritikhine, Chem. Eur. J., 2005, 11, 6994.

Synthesis and crystal structure of tetra- and hexanuclear uranium(IV) complexes with hexadentate compartmental Schiff base ligands.
L. Salmon, P. Thuéry and M. Ephritikhine, Dalton Trans., 2004, 4139-4145.

Synthesis and crystal structure of uranium(IV) complexes with compartmental Schiff bases: from mononuclear species to tri- and tetranuclear clusters.
L. Salmon, P. Thuery and M. Ephritikhine, Dalton Trans., 2004, 1635-1643.

Crystal structure of the first octanuclear uranium(IV) complex with compartmental Schiff base ligands.
L. Salmon, P. Thuery and M. Ephritikhine, Polyhedron, 2004, 23, 623-627.

Bis{bis[5-tert-butyl-2-oxido-3-(1-pyridiniomethyl)phenyl]methane}-dioxouranium bis(trifluoromethanesulfonate) pyridine disolvate: a uranyl bis(diphenoxide) complex resulting from homooxacalixarene cleavage.
L. Salmon, P. Thuery, M. Ephritikhine and B. Masci, Acta Crystallogr. Section C, 2004, 60, M27-M29.

Structure and magnetism of the first strictly dinuclear compound containing paramagnetic 3d and 5f metal ions. Major influence of the Cu-II ion coordination on the exchange Cu-II-U-IV interaction.
L. Salmon, P. Thuery, E. Riviere, J. J. Girerd and M. Ephritikhine, Chem. Comm., 2003, 6, 762-763.

Versatility of the nature of the magnetic Cu(II)-U(IV) interaction. Syntheses, crystal structures and magnetic properties of Cu2U and CuU compounds.
L. Salmon, P. Thuery, E. Riviere, J. J. Girerd and M. Ephritikhine, Dalton Trans., 2003, 2872-2880.

A bis(acetylacetonato)uranium(IV) complex of the Schiff base N,N'-bis(3-hydroxysalicylidene)-2-methyl-1,2-propanediamine.
L. Salmon, P. Thuery and M. Ephritikhine, Acta Crystallogr. Section C, 2003, 59, m246.

Complexes of uranium(IV) with acyclic polyphenoxides resulting from cleavage of homooxacalixarenes.
L. Salmon, P. Thuery, M. Ephritikhine, B. Masci, Dalton Trans., 2003, 2405-2410.

Crystal structure of hetero(bi- and tetra-)metallic complexes of compartmental Schiff bases uniting uranyl and transition metal (Ni2+, Cu2+) ions.
L. Salmon, P. Thuery and M. Ephritikhine, Polyhedron, 2003, 22, 2683-2688.